Vibrational excitation of H2O by electron impact

被引:9
|
作者
Moreira, O [1 ]
Thompson, DG
McLaughlin, BM
机构
[1] Univ Fribourg, Inst Phys Chem, CH-1700 Fribourg, Switzerland
[2] Univ York, Dept Phys, York YO10 5DD, N Yorkshire, England
[3] Queens Univ Belfast, Dept Appl Math & Theoret Phys, Belfast BT7 1NN, Antrim, North Ireland
关键词
D O I
10.1088/0953-4075/34/19/301
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We present results for the vibrational excitation of H2O by low-energy electrons (< 10 eV). We calculate differential cross sections for the first excited states for all three modes using an R-matrix approach, at the static-exchange level, and the Chase approximation. Correction to the scattering amplitude for all partial waves (l > 3) is made using a closure approximation. The results are consistent with other theoretical treatments. For the bending mode there is agreement with two older experiments but disagreement with a more recent experiment at 7.5 eV However, the present results for the stretch modes are less than the experimental values.
引用
收藏
页码:3737 / 3750
页数:14
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