We present results for the vibrational excitation of H2O by low-energy electrons (< 10 eV). We calculate differential cross sections for the first excited states for all three modes using an R-matrix approach, at the static-exchange level, and the Chase approximation. Correction to the scattering amplitude for all partial waves (l > 3) is made using a closure approximation. The results are consistent with other theoretical treatments. For the bending mode there is agreement with two older experiments but disagreement with a more recent experiment at 7.5 eV However, the present results for the stretch modes are less than the experimental values.
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Univ Paris Saclay, Cent Supelec, LGPM, 8-10 Rue Joliot Curie, F-91190 Gif Sur Yvette, FranceUniv Paris Saclay, Cent Supelec, LGPM, 8-10 Rue Joliot Curie, F-91190 Gif Sur Yvette, France
Ayouz, Mehdi
Faure, Alexandre
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Univ Grenoble Alpes, CNRS, IPAG, F-38000 Grenoble, FranceUniv Paris Saclay, Cent Supelec, LGPM, 8-10 Rue Joliot Curie, F-91190 Gif Sur Yvette, France
Faure, Alexandre
Tennyson, Jonathan
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UCL, Dept Phys & Astron, Gower St, London WC1E 6BT, EnglandUniv Paris Saclay, Cent Supelec, LGPM, 8-10 Rue Joliot Curie, F-91190 Gif Sur Yvette, France
Tennyson, Jonathan
Tudorovskaya, Maria
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Quantemol Ltd, 320 City Rd, London EC1V 2NZ, EnglandUniv Paris Saclay, Cent Supelec, LGPM, 8-10 Rue Joliot Curie, F-91190 Gif Sur Yvette, France