A Simple Hydrophilic Palladium(II) Complex as a Highly Efficient Catalyst for Room Temperature Aerobic Suzuki Coupling Reactions in Aqueous Media

被引：12

作者：

Guo, Mengping ^{[1
,2
]}

Liu, Shiwen ^{[1
,2
]}

Zhou, Xiuling ^{[1
]}

Lv, Meiyun ^{[1
]}

Chen, Sanbao ^{[1
]}

Xiao, Daoan ^{[1
]}

机构：

[1] Yichun Univ, Inst Coordinat Catalysis, Coll Chem & Bioengn, Yichun 336000, Peoples R China

[2] Yichun Univ, Ctr Engn, Jiangxi Univ Lithium Energy, Yichun 336000, Peoples R China

来源：

MOLECULES | 2014年 / 19卷 / 05期

基金：

中国国家自然科学基金;

关键词：

hydrophilic catalyst; aqueous media; green chemistry; Suzuki reaction; ARYL CHLORIDES; ORGANOBORON COMPOUNDS; ARYLBORONIC ACIDS; MIYAURA REACTIONS; GREEN CHEMISTRY; CROSS-COUPLINGS; WATER; BROMIDES; LIGAND; SONOGASHIRA;

D O I：

10.3390/molecules19056524

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A study on room temperature Suzuki cross-coupling in an aqueous medium was carried out using a simple hydrophilic palladium (II) complex, trans-PdCl2(NH2CH2COOH)(2) as catalyst in the presence of K2CO3 in air. This approach with a comparatively inexpensive and hydrophilic catalyst, mild reaction condition and aqueous media exhibits excellent catalytic activity towards the Suzuki coupling of aryl bromides and arylboronic acids, and good yields were obtained in the Suzuki coupling of activated aryl chlorides.

引用

页码：6524 / 6533

页数：10

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