Separation of cobalt and nickel using a thermomorphic ionic-liquid-based aqueous biphasic system

被引：63

作者：

Onghena, Bieke ^{[1
]}

Opsomer, Tomas ^{[1
]}

Binnemans, Koen ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Dept Chem, B-3001 Heverlee, Belgium

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 88期

关键词：

SOLVENT-EXTRACTION; RARE-EARTHS; METAL-IONS; TEMPERATURE; SALTS;

D O I：

10.1039/c5cc06595j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A [P-44414][Cl]-NaCl-H2O ionic liquid-based aqueous biphasic system shows promising results for the separation of cobalt(II) and nickel(II) by homogeneous liquid-liquid extraction. The extracting phase consists of a hydrophilic ionic liquid that is salted-out by sodium chloride, indicating that there is no need for using hydrophobic ionic liquids.

引用

页码：15932 / 15935

页数：4

共 33 条

[1] Selective separation of cadmium from cobalt, copper, iron (III) and zinc by water-based two-phase system of tetrabutylammonium bromide [J].

Akama, Y ;

Ito, M ;

Tanaka, S .

TALANTA, 2000, 53 (03) :645-650

[2] Environmentally Benign Sequential Extraction of Heavy Metals from Marine Sediments [J].

Alvarez, Maria S. ;

Gutierrez, Esther ;

Rodriguez, Ana ;

Angeles Sanroman, M. ;

Deive, Francisco J. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2014, 53 (20) :8615-8620

[3] Modulating the Solubilities of Ionic Liquid Components in Aqueous-Ionic Liquid Biphasic Systems: A Q-NMR Investigation [J].

Atanassova, Maria ;

Mazan, Valerie ;

Billard, Isabelle .

CHEMPHYSCHEM, 2015, 16 (08) :1703-1711

[4] Liquid-liquid extraction of actinides, lanthanides, and fission products by use of ionic liquids: from discovery to understanding [J].

Billard, Isabelle ;

Ouadi, Ali ;

Gaillard, Clotilde .

ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2011, 400 (06) :1555-1566

[5] Lanthanides and actinides in ionic liquids [J].

Binnemans, Koen .

CHEMICAL REVIEWS, 2007, 107 (06) :2592-2614

[6] Ionic liquids: Innovative fluids for chemical processing [J].

Brennecke, JF ;

Maginn, EJ .

AICHE JOURNAL, 2001, 47 (11) :2384-2389

[7] Can kosmotropic salt/chaotropic ionic liquid (salt/salt aqueous biphasic systems) be used to remove pertechnetate from complex salt waste? [J].

Bridges, Nicholas J. ;

Rogers, Robin D. .

SEPARATION SCIENCE AND TECHNOLOGY, 2008, 43 (05) :1083-1090

[8] Homogeneous liquid-liquid extraction of metal ions with non-fluorinated bis(2-ethylhexyl)phosphate ionic liquids having a lower critical solution temperature in combination with water [J].

Depuydt, Daphne ;

Liu, Liwang ;

Glorieux, Christ ;

Dehaen, Wim ;

Binnemans, Koen .

CHEMICAL COMMUNICATIONS, 2015, 51 (75) :14183-14186

[9] Effect of Temperature on Salt-Salt Aqueous Biphasic Systems: Manifestations of Upper Critical Solution Temperature [J].

Dilip, Meghna ;

Bridges, Nicholas J. ;

Rodriguez, Hector ;

Pereira, Jorge F. B. ;

Rogers, Robin D. .

JOURNAL OF SOLUTION CHEMISTRY, 2015, 44 (3-4) :454-468

[10] Overview of the Effect of Salts on Biphasic Ionic Liquid/Water Solvent Extraction Systems: Anion Exchange, Mutual Solubility, and Thermomorphic Properties [J].

Dupont, David ;

Depuydt, Daphne ;

Binnemans, Koen .

JOURNAL OF PHYSICAL CHEMISTRY B, 2015, 119 (22) :6747-6757

← 1 2 3 4 →