Hydrophosphinylation of unactivated alkenes with secondary phosphine oxides under visible-light photocatalysis

被引：106
作者：
Yoo, Woo-Jin [1 ]
Kobayashi, Shu [1 ]
机构：
[1] Univ Tokyo, Dept Chem, Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
来源：
GREEN CHEMISTRY | 2013年 / 15卷 / 07期
基金：
日本学术振兴会; 日本科学技术振兴机构;
关键词：
PHOSPHORUS-CENTERED RADICALS; CARBON BOND FORMATION; PHOTOREDOX CATALYSIS; P BOND; C-C; CHEMISTRY; FUNCTIONALIZATION; DERIVATIVES; REACTIVITY; ADDITIONS;
D O I：
10.1039/c3gc40482j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A visible light induced hydrophosphinylation of unactivated alkenes with diaryl phosphine oxides was found to occur with good yields and under mild reaction conditions in the presence of an inexpensive and commercially available organic dye as a photocatalyst.
引用
收藏
页码：1844 / 1848
页数：5
相关论文
共 50 条
  • [41] Cobaloxime Catalysis: Selective Synthesis of Alkenylphosphine Oxides under Visible Light
    Liu, Wen-Qiang
    Lei, Tao
    Zhou, Shuai
    Yang, Xiu-Long
    Li, Jian
    Chen, Bin
    Sivaguru, Jayaraman
    Tung, Chen-Ho
    Wu, Li-Zhu
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (35) : 13941 - 13947
  • [42] Visible-Light-Induced Cascade Phosphinoylation/Cyclization of Phenacylmalononitriles with Secondary H-phosphine Oxides
    Xiong, Biquan
    Shi, Chonghao
    Xu, Weifeng
    Liu, Yu
    Zhu, Longzhi
    Tang, Ke-Wen
    Yin, Shuang-Feng
    Wong, Wai-Yeung
    ADVANCED SYNTHESIS & CATALYSIS, 2022, 364 (24) : 4392 - 4401
  • [43] Visible-Light Induced Trifluoromethylation/Cyclization of Unactivated Alkene-Bound Quinazolinones
    Zou, Luqian
    Zhao, Hengyuan
    Wang, Xinming
    Dong, Jun
    Yang, Chungang
    Sun, Weiqing
    Xu, Jianbin
    Fan, Baomin
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2024, 27 (17)
  • [44] Synthesis of Isothiocyanates from Primary Amines via Visible-Light Photocatalysis
    Ma, Jinglin
    Li, Fengxi
    Wang, Chunyu
    Wang, Zhi
    Du, Chuang
    Wang, Lei
    ORGANIC LETTERS, 2023, 25 (30) : 5692 - 5696
  • [45] Chromium in Visible-Light Photocatalysis: Unique Reactivity, Mechanisms and Future Directions
    Shen, Zhengjia
    Tu, Jin-Lin
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2025, 28 (01)
  • [46] Gas sensitization and photochromism of CaTiO3-? for visible-light photocatalysis
    Chen, Jingwen
    Wang, Chong
    Li, Jibiao
    Ni, Jiupai
    Tang, Yu
    Irvine, John T. S.
    Ni, Chengsheng
    CHEMICAL ENGINEERING JOURNAL, 2023, 455
  • [47] Anti-Markovnikov Hydroazidation of Alkenes by Visible-Light Photoredox Catalysis
    Wang, Juan-Juan
    Yu, Wei
    CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (14) : 3510 - 3514
  • [48] Synthesis of Isoquinolines and Related Heterocycles under Visible-Light Conditions
    Yuan, Yurong
    Faure, Clara
    Menigaux, Doriane
    Berthelot, Mathieu
    Belmont, Philippe
    Brachet, Etienne
    JOURNAL OF ORGANIC CHEMISTRY, 2023, 88 (22) : 15750 - 15760
  • [49] Photocatalyzed Aerobic Dearomatization of Naphthylamines under Visible-Light Irradiation
    Voronov, Aleksandr
    Casnati, Alessandra
    Hoch, Matteo
    Pancrazzi, Francesco
    Mazzeo, Paolo Pio
    Merli, Daniele
    Maestri, Giovanni
    Feher, Peter Pal
    Stirling, Andras
    Capaldo, Luca
    Della Ca, Nicola
    ADVANCED SYNTHESIS & CATALYSIS, 2024, 366 (20) : 4187 - 4193
  • [50] Regioselective Dehydrogenation of the Secondary Amine Complexes into Imine Complexes under Visible-Light Irradiation
    Xiong, Ming-Feng
    Ye, Bao-Hui
    ORGANOMETALLICS, 2022, 41 (05) : 617 - 626
12345