Hydrophosphinylation of unactivated alkenes with secondary phosphine oxides under visible-light photocatalysis

被引：106
作者：
Yoo, Woo-Jin [1 ]
Kobayashi, Shu [1 ]
机构：
[1] Univ Tokyo, Dept Chem, Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
来源：
GREEN CHEMISTRY | 2013年 / 15卷 / 07期
基金：
日本学术振兴会; 日本科学技术振兴机构;
关键词：
PHOSPHORUS-CENTERED RADICALS; CARBON BOND FORMATION; PHOTOREDOX CATALYSIS; P BOND; C-C; CHEMISTRY; FUNCTIONALIZATION; DERIVATIVES; REACTIVITY; ADDITIONS;
D O I：
10.1039/c3gc40482j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A visible light induced hydrophosphinylation of unactivated alkenes with diaryl phosphine oxides was found to occur with good yields and under mild reaction conditions in the presence of an inexpensive and commercially available organic dye as a photocatalyst.
引用
收藏
页码：1844 / 1848
页数：5
相关论文
共 50 条
  • [31] Trifluoroethoxy-Coated Phthalocyanine Catalyzes Perfluoroalkylation of Alkenes under Visible-Light Irradiation
    Matsuzaki, Kohei
    Hiromura, Tomoya
    Amii, Hideki
    Shibata, Norio
    MOLECULES, 2017, 22 (07):
  • [32] Neutral-Eosin Y-Catalyzed Regioselective Hydroacylation of Aryl Alkenes under Visible-Light Irradiation
    Liu, Haiwang
    Xue, Fei
    Wang, Mu
    Tang, Xinxin
    Wu, Jie
    SYNLETT, 2021, 32 (04) : 406 - 410
  • [33] Controllable Remote C-H Bond Functionalization by Visible-Light Photocatalysis
    Hu, Xiao-Qiang
    Chen, Jia-Rong
    Xiao, Wen-Jing
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (08) : 1960 - 1962
  • [34] Visible-light-induced carbosulfonylation of unactivated alkenes via remote heteroaryl and oximino migration
    Tang, Nana
    Yang, Shan
    Wu, Xinxin
    Zhu, Chen
    TETRAHEDRON, 2019, 75 (12) : 1639 - 1646
  • [35] Phenylphenothiazine-Based Porous Organic Polymers as Visible-Light Heterogeneous Photocatalysts for Switchable Bromoalkylation and Cyclopropanation of Unactivated Terminal Alkenes
    Wang, Rui
    Zhou, Cen
    Huang, Xiaozhou
    Wu, Jun-Yan
    Zhang, Xiao
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2022, 10 (14) : 4650 - 4659
  • [36] Visible-light initiated direct oxysulfonylation of alkenes with sulfinic acids leading to β-ketosulfones
    Yang, Daoshan
    Huang, Ben
    Wei, Wei
    Li, Jin
    Lin, Gu
    Liu, Yaru
    Ding, Jiehua
    Sun, Pengfei
    Wang, Hua
    GREEN CHEMISTRY, 2016, 18 (20) : 5630 - 5634
  • [37] Recent advances of visible-light photocatalysis in the functionalization of organic compounds
    Srivastava, Vishal
    Singh, Pravin K.
    Singh, Praveen P.
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2022, 50
  • [38] Advances in asymmetric visible-light photocatalysis, 2015-2019
    Jiang, Chunhui
    Chen, Wei
    Zheng, Wen-Hua
    Lu, Hongfei
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2019, 17 (38) : 8673 - 8689
  • [39] Fragment Coupling with Tertiary Radicals Generated by Visible-Light Photocatalysis
    Jamison, Christopher R.
    Overman, Larry E.
    ACCOUNTS OF CHEMICAL RESEARCH, 2016, 49 (08) : 1578 - 1586
  • [40] Synthesis of α-functionalized ketones by visible-light promoted oxygenation of alkenes
    Gong, Xinchi
    Zhu, Chunyin
    Ye, Long-Wu
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2020, 18 (10) : 1843 - 1850
12345