A Multidimensional Undergraduate Experiment for Easy Solution and Surface Sensing of Mercury(II) and Copper(II) Metal Cations

被引：12

作者：

Espinosa, Arturo ^{[1
]}

Oton, Francisco ^{[1
]}

Martinez, Rosario ^{[1
]}

Tarraga, Alberto ^{[1
]}

Molina, Pedro ^{[1
]}

机构：

[1] Univ Murcia, Dept Quim Organ, E-30100 Murcia, Spain

来源：

JOURNAL OF CHEMICAL EDUCATION | 2013年 / 90卷 / 08期

关键词：

Second-Year Undergraduate; Analytical Chemistry; Environmental Chemistry; Laboratory Instruction; Organic Chemistry; Hands-On Learning/Manipulatives; Fluorescence Spectroscopy; Qualitative Analysis; Synthesis; Transition Elements; FLUORESCENT; MEMBRANES; SENSORS; CU2+; DERIVATIVES; STABILITY; DISCOVERY; TRANSPORT; RECEPTOR; LEAD;

D O I：

10.1021/ed300571s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The recently reported bis(1-pyrenyl)azine, easily prepared in a one-step reaction from 1-pyrenecarboxaldehyde and hydrazine hydrate, is used as a receptor for the visual detection of Hg2+ and Cu2+ ions in solution in an undergraduate laboratory experiment. The receptor was also supported on both filter paper and a hydrophobic PTFE (polytetrafluoroethylene) membrane, and the resulting probe-coated sheets were successfully used for selective sensing of the same metal ions using optical and fluorescent spectroscopies. This project provides an opportunity to organic chemistry students to learn about the challenging problem of selectively detecting toxic metal ions, such as Cu2+ and Hg2+, in solution.

引用

页码：1057 / 1060

页数：4

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