Effect of Al2O3 content on the mechanical and interdiffusional properties of ion-exchanged Na-aluminosilicate glasses

被引:23
作者
Ragoen, C. [1 ]
Sen, S. [2 ]
Lambricht, T. [3 ]
Godet, S. [1 ]
机构
[1] Univ Libre Bruxelles, Dept 4MAT, CP165-63,Ave F Roosevelt 50, B-1050 Brussels, Belgium
[2] Univ Calif Davis, Dept Mat Sci & Engn, Davis, CA 95616 USA
[3] AGC Glass Europe, Technovat Ctr, Rue Louis Bleriot 12, B-6041 Gosselies, Belgium
关键词
Glass; Aluminosilicate; Diffusion; Chemical tempering; Structure; Ion exchange; CHEMICALLY TEMPERED GLASSES; YOUNGS MODULUS; SODIUM; DIFFUSION; INDENTATION; BEHAVIOR; KINETICS;
D O I
10.1016/j.jnoncrysol.2016.12.019
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The effect of the variation in the Al2O3 content on select physical properties of pristine and ion-exchanged glasses in the systems: (75 - x)SiO(2)mol%-25Na(2)O-xAl(2)O(3) and (75 - x)SiO2-15Na(2)O-10CaO-xAl(2)O(3), are reported. The surface compressive stress, surface hardness and K+/Na+ exchange ratio increase, while the depth of the inter diffusion distance decreases, with increasing Al2O3 content. These trends art shown to be consistent with the compositional variation of the glass transition temperature and the molar volume, and their atomistic and thermodynamic bases are discussed. (C) 2016 Elsevier B.V. All rights reserved.
引用
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页码:129 / 136
页数:8
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