Iron(III) chloride and its coordination chemistry

被引：27

作者：

Cotton, Simon A. ^{[1
]}

机构：

[1] Univ Birmingham, Sch Chem, Birmingham, W Midlands, England

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2018年 / 71卷 / 21期

关键词：

Iron; Fe(III); structures; coordination chemistry; X-RAY CRYSTAL; ELECTRON-PARAMAGNETIC-RESONANCE; LOW-TEMPERATURE MAGNETISM; MOLECULAR-STRUCTURE; DIMETHYL-SULFOXIDE; IRON TRICHLORIDE; ALPHA; ALPHA-DIIMINE SYSTEM; TRIPHENYLPHOSPHINE OXIDE; HETEROLIGAND COMPLEXES; NEUTRON-DIFFRACTION;

D O I：

10.1080/00958972.2018.1519188

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination chemistry of FeCl3 is distinctly different to that of the other 3d metal halides. It has a distinct preference for O-donor ligands. Although it primarily forms six-coordinate complexes, it has some distinctive features that set it apart from metals like Mn(II), Co(II), and Ni(II), such as the self-ionized complexes [FeL4Cl2](+) [FeCl4](-). There are a number of examples where very small changes in the coordination sphere tilt the balance between isomeric structures. Chloride has a significant steric effect in the coordination sphere as well as a greater trans-influence than water. [GRAPHICS] .

引用

页码：3415 / 3443

页数：29

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