Iron(III) chloride and its coordination chemistry

被引：27

作者：

Cotton, Simon A. ^{[1
]}

机构：

[1] Univ Birmingham, Sch Chem, Birmingham, W Midlands, England

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2018年 / 71卷 / 21期

关键词：

Iron; Fe(III); structures; coordination chemistry; X-RAY CRYSTAL; ELECTRON-PARAMAGNETIC-RESONANCE; LOW-TEMPERATURE MAGNETISM; MOLECULAR-STRUCTURE; DIMETHYL-SULFOXIDE; IRON TRICHLORIDE; ALPHA; ALPHA-DIIMINE SYSTEM; TRIPHENYLPHOSPHINE OXIDE; HETEROLIGAND COMPLEXES; NEUTRON-DIFFRACTION;

D O I：

10.1080/00958972.2018.1519188

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination chemistry of FeCl3 is distinctly different to that of the other 3d metal halides. It has a distinct preference for O-donor ligands. Although it primarily forms six-coordinate complexes, it has some distinctive features that set it apart from metals like Mn(II), Co(II), and Ni(II), such as the self-ionized complexes [FeL4Cl2](+) [FeCl4](-). There are a number of examples where very small changes in the coordination sphere tilt the balance between isomeric structures. Chloride has a significant steric effect in the coordination sphere as well as a greater trans-influence than water. [GRAPHICS] .

引用

页码：3415 / 3443

页数：29

共 161 条

[1] CROWN-ETHER COMPLEXES WITH SOME TRANSITION-METALS [J].

ABRAHIM, J ;

MARJI, D .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 101 (03) :L23-L24

[2] SINGLE-CRYSTAL RAMAN STUDY OF SOME AQUO-PENTACHLORO-SALTS [MCI5-(H2O)]2- (M = IN OR FE) [J].

ADAMS, DM ;

NEWTON, DC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (05) :681-&

[3] SURVEY STUDY OF VIBRATIONAL SPECTRA OF SOME AQUO-HALOGENO-COMPLEXES [J].

ADAMS, DM ;

LOCK, PJ .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (17) :2801-&

[4] MANGANESE(II) AND IRON(III) COMPLEXES OF THE TRIDENTATE LIGANDS BIS(BENZ-IMIDAZOL-2-YLMETHYL)-AMINE (L1) AND BIS(BENZ-IMIDAZOL-2-YLMETHYL)-METHYLAMINE (L2) - CRYSTAL-STRUCTURES OF [MNL1(CH3CO2)2], [FEL2CL3], AND [FE2L12(MU-O)(MU-(CH3)3CCO2)2][CLO4]2 [J].

ADAMS, H ;

BAILEY, NA ;

CRANE, JD ;

FENTON, DE ;

LATOUR, JM ;

WILLIAMS, JM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (05) :1727-1735

[5] The molten state of iron trichloride: A molecular ionic conductor [J].

Akdeniz, Z ;

Tosi, MP .

NUOVO CIMENTO DELLA SOCIETA ITALIANA DI FISICA D-CONDENSED MATTER ATOMIC MOLECULAR AND CHEMICAL PHYSICS FLUIDS PLASMAS BIOPHYSICS, 1998, 20 (7-8) :1111-1116

[6] Iron(III) mixed-ligand complexes:: Synthesis, characterization and crystal structure determination of iron(III) hetero-ligand complexes containing 1,10-phenanthroline, 2,2′-bipyridine, chloride and dimethyl sulfoxide, [Fe(phen)Cl3(DMSO)] and [Fe(bipy)Cl3(DMSO)] [J].

Amani, Vahid ;

Safari, Nasser ;

Khavasi, Hamid Reza ;

Mirzaei, Peiman .

POLYHEDRON, 2007, 26 (17) :4908-4914

[7] Synthesis, characterization and crystal structure determination of iron(III) hetero-ligand complexes containing 2,2′-bipyridine, 5,5′-dimethyl-2,2′-bipyridine and chloride, [Fe(bipy)Cl4][bipy•H] and [Fe(dmbipy)2Cl2][FeCl4] [J].

Amani, Vahid ;

Safari, Nasser ;

Khavasi, Hamid Reza .

POLYHEDRON, 2007, 26 (15) :4257-4262

[8] Iron(III) hetero-ligand complexes containing 1,10-phenanthroline derivatives, chloride and dimethyl sulfoxide: synthesis, characterization, crystal structure determination and luminescent properties [J].

Amani, Vahid ;

Safari, Nasser ;

Notash, Behrouz .

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2013, 10 (04) :751-761

[9] Synthesis, characterization and crystal structure determination of iron(III) complexes containing 4,4'-dimethyl-2,2'-bipyridine, dimethyl sulfoxide and chloride, [Fe(dmbipy)Cl4][dmbipyH] and [Fe(dmbipy)Cl3(DMSO)] [J].

Amani, Vahid ;

Safari, Nasser ;

Notash, Behrouz ;

Khavasi, Hamid Reza .

JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (12) :1939-1950

[10] A simple combination of higher-oxidation-state FeX3 and phosphine or amine ligand for living radical polymerization of styrene, methacrylate, and acrylate [J].

Aoshima, Hiroshi ;

Satoh, Kotaro ;

Umemura, Tomonari ;

Kamigaito, Masami .

POLYMER CHEMISTRY, 2013, 4 (12) :3554-3562

← 1 2 3 4 5 6 7 8 9 10 →