Horseradish peroxidase-mediated oxidation of carcinogenic non-aminoazo dyes

被引:0
|
作者
Zhu, M [1 ]
Huang, XM
Shen, HX
机构
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Chinese Acad Sci, Univ Sci & Technol, Grad Sch, Beijing 100039, Peoples R China
关键词
non-aminoazo dyes; carcinogenesis; HRP/H2O2; system;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fifteen non-aminoazo dyes were oxidized when catalyzed by horseradish peroxidase (HRP) in the presence of H2O2. Aromaticdiazonium ions, the ultimate carcinogen, were detected in the reaction with an of aza compounds as the substrates for HRP. The rates of oxidative cleavage fairly depended on pH. Relative enzymatic activities were compared among 15 non-aminoazo, dyes, and the structural requirements of the substrates for HRP were discussed in detail.
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页码:356 / 362
页数:7
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