Preparation and Characterization of Phosphate Glasses Co-doped with Rare Earth Ions

被引:9
作者
Elbakey, A. A. [1 ]
Farag, M. A. [2 ]
El-Okr, M. [2 ]
Elrasasi, T. Y. [1 ]
El-Mansy, M. K. [1 ]
机构
[1] Benha Univ, Fac Sci, Phys Dept, Banha, Egypt
[2] El Azhar Univ, Phys Dept, Fac Sci, Cairo, Egypt
来源
EGYPTIAN JOURNAL OF CHEMISTRY | 2020年 / 63卷 / 05期
关键词
Rare earth element; Phosphate glass; Structural properties; SPECTROSCOPIC PROPERTIES; BROAD-BAND; TRANSITION TEMPERATURE; OPTICAL-PROPERTIES; EMISSION; LUMINESCENCE; BORATE; ER3+; FTIR; MGO;
D O I
10.21608/ejchem.2019.15556.1944
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
SAMARIUM zinc sodium phosphate glasses doped by different Er2O3 concentrations were prepared using a conventional melt quenching technique. The structural properties due to the influence of Er+3 ions on the presented glass network were investigated. XRD pattern confirms samples amorphousity. Surface morphology using SEM proved the non-crystallinity and the homogeneity of the samples. The elemental composition using EDAX analysis gave an acceptable mass percentage of the constituent's elements. FTIR revealed the formation of Non-Bridging oxygen (NBO). The measured density, molar volume, ion concentration, interatomic distance, polaron radius and field strength have been studied with respect to the concentration of Er+3.
引用
收藏
页码:1955 / 1964
页数:10
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