Transition metal-containing macromolecules: En route to new functional materials

被引:97
作者
Abd-El-Aziz, Alaa S. [1 ,2 ]
Strohm, Elizabeth A. [2 ]
机构
[1] Univ Prince Edward Isl, Dept Chem, Charlottetown, PE C1A 4P3, Canada
[2] Univ British Columbia, Dept Chem, Kelowna, BC V1V 1V7, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
Organometallic polymers; Coordination polymers; Metallocene-based systems; RING-OPENING POLYMERIZATION; LIVING ANIONIC-POLYMERIZATION; CONTAINING POLYMERS; ORGANOMETALLIC POLYMERS; COORDINATION POLYMERS; BLOCK-COPOLYMERS; SUPRAMOLECULAR ISOMERISM; DENDRITIC MACROMOLECULES; MOLECULAR ARCHITECTURE; CARBOSILANE DENDRIMERS;
D O I
10.1016/j.polymer.2012.08.024
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Recent development in the field of organometallic and coordination polymers based on transition metals, particularly the methods and degree of polymerization, the nature of bonding present, and the type of metal moiety, has become an area of ever-growing interest. Metal-containing polymers have catalytic, magnetic, optical, electrical, and electrochemical properties which allow for a variety of applications. This review will mainly shed light on the past five years of research in organometallic and coordination polymers containing transition metals, focusing on the synthetic methodologies, structural properties, and applications. (c) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4879 / 4921
页数:43
相关论文
共 228 条
  • [21] Amperometric enzyme electrodes for aerobic and anaerobic glucose monitoring prepared by glucose oxidase immobilized in mixed ferrocene-cobaltocenium dendrimers
    Alonso, B
    Armada, PG
    Losada, J
    Cuadrado, I
    González, B
    Casado, CM
    [J]. BIOSENSORS & BIOELECTRONICS, 2004, 19 (12) : 1617 - 1625
  • [22] New functional polymers and materials based on 2,2′:6′,2"-terpyridine metal complexes
    Andres, PR
    Schubert, US
    [J]. ADVANCED MATERIALS, 2004, 16 (13) : 1043 - 1068
  • [23] Catalysts based on palladium dendrimers
    Andres, Roman
    de Jesus, Ernesto
    Carlos Flores, Juan
    [J]. NEW JOURNAL OF CHEMISTRY, 2007, 31 (07) : 1161 - 1191
  • [24] 3d-4f Combined Chemistry: Synthetic Strategies and Magnetic Properties
    Andruh, Marius
    Costes, Jean-Pierre
    Diaz, Carmen
    Gao, Song
    [J]. INORGANIC CHEMISTRY, 2009, 48 (08) : 3342 - 3359
  • [25] Single and double metallic layer-containing ruthenium dendrimers. Synthesis and catalytic properties
    Angurell, I
    Muller, G
    Rocamora, M
    Rossell, O
    Seco, M
    [J]. DALTON TRANSACTIONS, 2004, (16) : 2450 - 2457
  • [26] Synthesis and catalytic properties of neutral and cationic rhodium- and iridium-containing carbosilane dendrimers
    Angurell, I
    Muller, G
    Rocamora, M
    Rossell, O
    Seco, M
    [J]. DALTON TRANSACTIONS, 2003, (06) : 1194 - 1200
  • [27] Synthesis of Carbosilane Dendrimers Containing up to Four Metal Layers
    Angurell, Inma
    Rossell, Oriol
    Seco, Miquel
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (12) : 2932 - 2940
  • [28] Hydroformylation activity of multinuclear rhodium complexes coordinated to dendritic iminopyridyl and iminophosphine scaffolds
    Antonels, Nathan C.
    Moss, John R.
    Smith, Gregory S.
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (10) : 2003 - 2007
  • [29] Synthesis of carbosilane dendrimers containing peripheral (cyclopentadienyl)(aryloxy)titanium(IV) units
    Arévalo, S
    de Jesús, E
    de la Mata, FJ
    Flores, JC
    Gómez, R
    [J]. ORGANOMETALLICS, 2001, 20 (12) : 2583 - 2592
  • [30] Astruc D, 2000, TOP CURR CHEM, V210, P229