Synthesis of oligophenylenevinylene heptamers substituted with fullerene moieties

被引：13
作者：
Gegout, Aline G. [1 ,2 ]
Holler, Michel [1 ,2 ]
Figueira-Duarte, Teresa M. [1 ,2 ]
Nierengarten, Jean-Francois [1 ,2 ]
机构：
[1] Univ Strasbourg, Lab Chim Mat Mol, F-67087 Strasbourg 2, France
[2] Ecole Europeenne Chim Polymeres & Mat, CNRS, UMR 7509, F-67087 Strasbourg 2, France
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 2008卷 / 21期
关键词：
conjugated systems; fullerene; oligophenylenevinylene;
D O I：
10.1002/ejoc.200800312
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Oligophenylenevinylene (OPV) derivatives substituted with one or two fullerene subunits have been prepared starting from a fullerene carboxylic acid derivative and OPV heptamers bearing one or two alcohol functions. The electrochemical properties of the resulting C-60-OPV derivatives have been investigated by cyclic voltammetry. Whereas the fist reduction of both C-60-OPV conjugates is centered on the C-60 unit, the oxidation is centered on the OPV rod. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 6945t Weinheim, Germany, 2008).
引用
收藏
页码：3627 / 3634
页数：8
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