Iron-Catalyzed Hydrosilylation of Esters

被引：99
|
作者：
Bezier, David [1 ]
Venkanna, Gopaladasu T. [1 ]
Castro, Luis C. Misal [1 ]
Zheng, Jianxia [1 ]
Roisnel, Thierry [2 ]
Sortais, Jean-Baptiste [1 ]
Darcel, Christophe [1 ]
机构：
[1] Univ Rennes 1, Inst Sci Chim Rennes, Team Organometall Mat & Catalysis, CNRS,UR1,UMR 6226, F-35042 Rennes, France
[2] Univ Rennes 1, Inst Sci Chim Rennes, Team Ctr Diffractomtrie X, CNRS,UR1,UMR 6226, F-35042 Rennes, France
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 10期
关键词：
alcohols; esters; hydrosilylation; iron catalysis; reduction; CARBOXYLIC-ACID DERIVATIVES; METAL HYDRIDE CATALYSTS; EFFICIENT HYDROSILYLATION; SELECTIVE REDUCTION; CARBONYL-COMPOUNDS; ASYMMETRIC HYDROSILYLATION; HYDROSILANE REDUCTION; PINCER LIGANDS; KETONES; ALCOHOLS;
D O I：
10.1002/adsc.201200087
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The first hydrosilylation of esters catalyzed by a well defined iron complex has been developed. Esters are converted to the corresponding alcohols at 100?degrees C, under solvent-free conditions and visible light activation.
引用
收藏
页码：1879 / 1884
页数：6
相关论文
共 50 条
  • [41] Expedient Iron-Catalyzed Coupling of Alkyl, Benzyl and Allyl Halides with Arylboronic Esters
    Bedford, Robin B.
    Brenner, Peter B.
    Carter, Emma
    Carvell, Thomas W.
    Cogswell, Paul M.
    Gallagher, Timothy
    Harvey, Jeremy N.
    Murphy, Damien M.
    Neeve, Emily C.
    Nunn, Joshua
    Pye, Dominic R.
    CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (26) : 7935 - 7938
  • [42] THIOCYANATIONS-VI - IRON-CATALYZED THIOCYANATIONS OF UNSATURATED-ACIDS AND ESTERS
    MAXWELL, RJ
    SILBERT, LS
    JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1978, 55 (07) : 583 - 586
  • [43] Iron-Catalyzed Arene Prenylation
    Villani-Gale, Alexander J.
    Eichman, Chad C.
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 2016 (17) : 2925 - 2928
  • [44] Iron-catalyzed synthesis of cinnarizine
    Shakhmaev, R. N.
    Sunagatullina, A. Sh
    Zorin, V. V.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2015, 51 (01) : 95 - 97
  • [45] Iron-Catalyzed Hydromagnesiation of Olefins
    Greenhalgh, Mark D.
    Thomas, Stephen P.
    SYNLETT, 2013, 24 (05) : 531 - 534
  • [46] Iron-Catalyzed Isomerizations of Olefins
    Mayer, Matthias
    Welther, Alice
    Jacobi von Wangelin, Axel
    CHEMCATCHEM, 2011, 3 (10) : 1567 - 1571
  • [47] IRON-CATALYZED ALLYLIC ALKYLATION
    LADOULIS, SJ
    NICHOLAS, KM
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 285 (1-3) : C13 - C16
  • [48] Iron-catalyzed synthesis of cinnarizine
    R. N. Shakhmaev
    A. Sh. Sunagatullina
    V. V. Zorin
    Russian Journal of Organic Chemistry, 2015, 51 : 95 - 97
  • [49] Iron-Catalyzed Hydroboration of Vinylcyclopropanes
    Chen, Chenhui
    Shen, Xuzhong
    Chen, Jianhui
    Hong, Xin
    Lu, Zhan
    ORGANIC LETTERS, 2017, 19 (19) : 5422 - 5425
  • [50] Iron-Catalyzed Synthesis of (E)-β-Vinylsilanes via a Regio- and Stereoselective Hydrosilylation from Terminal Alkynes
    Liu, Zhi-Kai
    Zhang, Guo-Liang
    Li, Ding-Chang
    Yang, Ying
    Chen, Li
    Zhan, Zhuang-Ping
    SYNLETT, 2019, 30 (02) : 235 - 239
12345