Iron-Catalyzed Hydrosilylation of Esters

被引：99
|
作者：
Bezier, David [1 ]
Venkanna, Gopaladasu T. [1 ]
Castro, Luis C. Misal [1 ]
Zheng, Jianxia [1 ]
Roisnel, Thierry [2 ]
Sortais, Jean-Baptiste [1 ]
Darcel, Christophe [1 ]
机构：
[1] Univ Rennes 1, Inst Sci Chim Rennes, Team Organometall Mat & Catalysis, CNRS,UR1,UMR 6226, F-35042 Rennes, France
[2] Univ Rennes 1, Inst Sci Chim Rennes, Team Ctr Diffractomtrie X, CNRS,UR1,UMR 6226, F-35042 Rennes, France
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 10期
关键词：
alcohols; esters; hydrosilylation; iron catalysis; reduction; CARBOXYLIC-ACID DERIVATIVES; METAL HYDRIDE CATALYSTS; EFFICIENT HYDROSILYLATION; SELECTIVE REDUCTION; CARBONYL-COMPOUNDS; ASYMMETRIC HYDROSILYLATION; HYDROSILANE REDUCTION; PINCER LIGANDS; KETONES; ALCOHOLS;
D O I：
10.1002/adsc.201200087
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The first hydrosilylation of esters catalyzed by a well defined iron complex has been developed. Esters are converted to the corresponding alcohols at 100?degrees C, under solvent-free conditions and visible light activation.
引用
收藏
页码：1879 / 1884
页数：6
相关论文
共 50 条
  • [31] Iron-catalyzed [4
    Wu, Qinghuan
    Li, Luchao
    Xu, Binyan
    Sun, Jie
    Ji, Dong
    Li, Yuguang
    Shen, Lei
    Fang, Zheng
    Duan, Jindian
    Chen, Beining
    Guo, Kai
    GREEN SYNTHESIS AND CATALYSIS, 2023, 4 (02): : 150 - 153
  • [32] Iron-catalyzed [4
    Duan, Jindian
    Xu, Gaochen
    Rong, Binsen
    Yan, Huan
    Zhang, Sai
    Wu, Qinghuan
    Zhu, Ning
    Guo, Kai
    GREEN SYNTHESIS AND CATALYSIS, 2021, 2 (02): : 237 - 240
  • [33] Iron-Catalyzed Asymmetric Hydrosilylation of Vinylcyclopropanes via Stereospecific C-C Bond Cleavage
    Chen, Chenhui
    Wang, Hongliang
    Sun, Yufeng
    Cui, Jiayan
    Xie, Jianbo
    Shi, Yang
    Yu, Shijia
    Hong, Xin
    Lu, Zhan
    ISCIENCE, 2020, 23 (04)
  • [34] Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation
    Meng-Yang Hu
    Qiao He
    Song-Jie Fan
    Zi-Chen Wang
    Luo-Yan Liu
    Yi-Jiang Mu
    Qian Peng
    Shou-Fei Zhu
    Nature Communications, 9
  • [35] Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation
    Hu, Meng-Yang
    He, Qiao
    Fan, Song-Jie
    Wang, Zi-Chen
    Liu, Luo-Yan
    Mu, Yi-Jiang
    Peng, Qian
    Zhu, Shou-Fei
    NATURE COMMUNICATIONS, 2018, 9
  • [36] A Concise Route to Cyclic Amines from Nitroarenes and Ketoacids under Iron-Catalyzed Hydrosilylation Conditions
    Wu, Jiajun
    Tongdee, Satawat
    Ammaiyappan, Yuvaraj
    Darcel, Christophe
    ADVANCED SYNTHESIS & CATALYSIS, 2021, 363 (15) : 3859 - 3865
  • [37] Iron-catalyzed hydrosilylation of CO2: CO2 conversion to formamides and methylamines
    Frogneux, Xavier
    Jacquet, Olivier
    Cantat, Thibault
    CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (06) : 1529 - 1533
  • [38] Aryl-aryl interactions as directing motifs in the stereodivergent iron-catalyzed hydrosilylation of internal alkynes
    Belger, Christian
    Plietker, Bernd
    CHEMICAL COMMUNICATIONS, 2012, 48 (44) : 5419 - 5421
  • [39] Iron-catalyzed carbonylative cyclization of γ,δ-unsaturated aromatic oxime esters to functionalized pyrrolines
    Zhang, Youcan
    Yin, Zhiping
    Wang, Hai
    Wu, Xiao-Feng
    CHEMICAL COMMUNICATIONS, 2020, 56 (51) : 7045 - 7048
  • [40] Iron-Catalyzed Sulfonylthiocyanation of α,β-Unsaturated Amides/Esters via the Insertion of Sulfur Dioxide
    Jia, Xiuwen
    Luo, Liping
    Huang, Chunxi
    Zhang, Xuemei
    Lian, Zhong
    ORGANIC LETTERS, 2022, 24 (41) : 7560 - 7565
12345