Iron-Catalyzed Hydrosilylation of Esters

被引：99
|
作者：
Bezier, David [1 ]
Venkanna, Gopaladasu T. [1 ]
Castro, Luis C. Misal [1 ]
Zheng, Jianxia [1 ]
Roisnel, Thierry [2 ]
Sortais, Jean-Baptiste [1 ]
Darcel, Christophe [1 ]
机构：
[1] Univ Rennes 1, Inst Sci Chim Rennes, Team Organometall Mat & Catalysis, CNRS,UR1,UMR 6226, F-35042 Rennes, France
[2] Univ Rennes 1, Inst Sci Chim Rennes, Team Ctr Diffractomtrie X, CNRS,UR1,UMR 6226, F-35042 Rennes, France
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 10期
关键词：
alcohols; esters; hydrosilylation; iron catalysis; reduction; CARBOXYLIC-ACID DERIVATIVES; METAL HYDRIDE CATALYSTS; EFFICIENT HYDROSILYLATION; SELECTIVE REDUCTION; CARBONYL-COMPOUNDS; ASYMMETRIC HYDROSILYLATION; HYDROSILANE REDUCTION; PINCER LIGANDS; KETONES; ALCOHOLS;
D O I：
10.1002/adsc.201200087
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The first hydrosilylation of esters catalyzed by a well defined iron complex has been developed. Esters are converted to the corresponding alcohols at 100?degrees C, under solvent-free conditions and visible light activation.
引用
收藏
页码：1879 / 1884
页数：6
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