Iron-Catalyzed Hydrosilylation of Esters

被引：99
作者：
Bezier, David [1 ]
Venkanna, Gopaladasu T. [1 ]
Castro, Luis C. Misal [1 ]
Zheng, Jianxia [1 ]
Roisnel, Thierry [2 ]
Sortais, Jean-Baptiste [1 ]
Darcel, Christophe [1 ]
机构：
[1] Univ Rennes 1, Inst Sci Chim Rennes, Team Organometall Mat & Catalysis, CNRS,UR1,UMR 6226, F-35042 Rennes, France
[2] Univ Rennes 1, Inst Sci Chim Rennes, Team Ctr Diffractomtrie X, CNRS,UR1,UMR 6226, F-35042 Rennes, France
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 10期
关键词：
alcohols; esters; hydrosilylation; iron catalysis; reduction; CARBOXYLIC-ACID DERIVATIVES; METAL HYDRIDE CATALYSTS; EFFICIENT HYDROSILYLATION; SELECTIVE REDUCTION; CARBONYL-COMPOUNDS; ASYMMETRIC HYDROSILYLATION; HYDROSILANE REDUCTION; PINCER LIGANDS; KETONES; ALCOHOLS;
D O I：
10.1002/adsc.201200087
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The first hydrosilylation of esters catalyzed by a well defined iron complex has been developed. Esters are converted to the corresponding alcohols at 100?degrees C, under solvent-free conditions and visible light activation.
引用
收藏
页码：1879 / 1884
页数：6
相关论文
共 79 条
  • [1] Addis, 2011, ANGEW CHEM, V123, P6128
  • [2] Selective Reduction of Carboxylic Acid Derivatives by Catalytic Hydrosilylation
    Addis, Daniele
    Das, Shoubhik
    Junge, Kathrin
    Beller, Matthias
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (27) : 6004 - 6011
  • [3] Chemo- and Stereoselective Iron-Catalyzed Hydrosilylation of Ketones
    Addis, Daniele
    Shaikh, Nadim
    Zhou, Shaolin
    Das, Shoubhik
    Junge, Kathrin
    Beller, Matthius
    [J]. CHEMISTRY-AN ASIAN JOURNAL, 2010, 5 (07) : 1687 - 1691
  • [4] [Anonymous], 2006, ANGEW CHEM, DOI DOI 10.1002/ANGE.200503771
  • [5] [Anonymous], 2007, ANGEW CHEM INT EDIT
  • [6] [Anonymous], 2007, The Handbook of Homogeneous Hydrogenation
  • [7] TITANOCENE-CATALYZED REDUCTION OF ESTERS USING POLYMETHYLHYDROSILOXANE AS THE STOICHIOMETRIC REDUCTANT
    BARR, KJ
    BERK, SC
    BUCHWALD, SL
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (15) : 4323 - 4326
  • [8] A CATALYTIC METHOD FOR THE REDUCTION OF ESTERS TO ALCOHOLS
    BERK, SC
    KREUTZER, KA
    BUCHWALD, SL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (13) : 5093 - 5095
  • [9] AN AIR-STABLE CATALYST SYSTEM FOR THE CONVERSION OF ESTERS TO ALCOHOLS
    BERK, SC
    BUCHWALD, SL
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (14) : 3751 - 3753
  • [10] Cyclopentadienyl-NHC Iron Complexes for Solvent-Free Catalytic Hydrosilylation of Aldehydes and Ketones
    Bezier, David
    Jiang, Fan
    Roisnel, Thierry
    Sortais, Jean-Baptiste
    Darcel, Christophe
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (09) : 1333 - 1337
12345678