Stabilization of polystyrene by styrylquinoline containing methacrylates

被引：1
作者：
Kharchenko, Oksana [1 ]
Smokal, Vitaliy [1 ]
Krupka, Oksana [1 ]
Virych, Pavlo [1 ]
Kutsevol, Natalia [1 ]
机构：
[1] Kyiv Taras Shevchenko Natl Univ, Kiev, Ukraine
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2020年 / 699卷 / 01期
关键词：
Methacrylic monomers; polystyrene; styrylquinoline containing monomers; thermal stabilization; POLYMERS;
D O I：
10.1080/15421406.2020.1732538
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The thermostability of polysterene with/without new styrylquinoline containing methacrylic fragments has been described in the present work. Polystyrene and copolymers based on styrene and new methacrylic styrylquinoline containing monomers were synthesized by free radical thermoinitiated polymerization in the presence of 2,2 '-azobisisobutyronitrile (1 wt%) as initiator at inert atmosphere. The impact of 2-[2-(4-methoxyphenyl)ethenyl]quinolin-8-yl 2-methylpropyl-2-enoate (\M1), 2-(2-phenylethenyl)quinolin-8-yl 2-methylpropyl-2-enoate (\M2), 2-[2-(4-nitrophenyl)ethenyl]quinolin-8-yl 2-methylpropyl-2-enoate (\M3) on thermal stability of polystyrene was investigated. The thermostability of polystyrene and copolymers ST:M1, ST:M2, ST:M3 were studied by dynamic thermograviametric analysis. It was shown that destruction of polystyrene with corresponding units M1-M2 starts at 41-42 degrees C higher, than reference polystyrene.
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页码：51 / 56
页数：6
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共 13 条
  • [1] Thermal degradation of high-impact polystyrene with pro-oxidant additives
    Arraez, Francisco J.
    Luisa Arnal, Maria
    Mueller, Alejandro J.
    [J]. POLYMER BULLETIN, 2019, 76 (03) : 1489 - 1515
  • [2] Cherezova E. N., 2012, AGING STABILIZATION, P150
  • [3] Aromatic compounds with a 3a,6a-dihydrofuro[2,3-b]furan moiety .3. Novel stabilizer for polystyrene at higher temperatures
    Fan, XB
    Okazaki, H
    Yamaye, M
    Hamada, T
    Yanai, T
    Takemura, S
    Kito, T
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1996, 35 (10) : 3431 - 3436
  • [4] Synthesis and optical properties of copolymers of 4-aminostyrene with the side styrylquinoline chromophore groups
    Goikhman, M. Ya.
    Subbotina, L. I.
    Martynenkov, A. A.
    Smirnov, M. A.
    Smyslov, R. Yu.
    Popova, E. N.
    Yakimanskii, A. V.
    [J]. RUSSIAN CHEMICAL BULLETIN, 2011, 60 (02) : 295 - 303
  • [5] KINETIC-MODEL OF THE MECHANISM OF HIGH-TEMPERATURE INHIBITED OXIDATION OF POLYMERS
    GOLDBERG, VM
    VIDOVSKAYA, LA
    ZAIKOV, GE
    [J]. POLYMER DEGRADATION AND STABILITY, 1988, 20 (02) : 93 - 121
  • [6] UV irradiation induce NLO modulation in photochromic styrylquinoline-based polymers: Computational and experimental studies
    Guichaoua, Dominique
    Kulyk, Bohdan
    Smokal, Vitaliy
    Migalska-Zalas, Anna
    Kharchenko, Oksana
    Krupka, Oksana
    Kolendo, Oleksiy
    Sahraoui, Bouchta
    [J]. ORGANIC ELECTRONICS, 2019, 66 : 175 - 182
  • [7] Maleimidophenylmethacrylates and their derivatives as polystyrene thermal stabilizers
    Iepishkina, Iu.
    Iukhymenko, N.
    Kolendo, A.
    Demchenko, O.
    Shyichuk, A.
    [J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2008, 486 : 1382 - 1389
  • [8] Krupka O., 2019, SPRINGER P PHYS, V222, P131, DOI [10.1007/978-3-030-17755-3_9, DOI 10.1007/978-3-030-17755-3_9]
  • [9] ANTIOXIDANT ACTION IN POLYMERS - THE ROLE OF INERT COMPOUNDS IN INHIBITED OXIDATION
    SHLYAPNIKOV, YA
    MARIN, AP
    [J]. POLYMER DEGRADATION AND STABILITY, 1993, 40 (03) : 337 - 341
  • [10] Synthesis and photophysical properties of new styrylquinoline-containing polymers
    Smokal, Vitaliy
    Krupka, Anastasia
    Kharchenko, Oksana
    Krupka, Oksana
    Derkowska-Zielinska, Beata
    Kolendo, Aleksey
    [J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2018, 661 (01) : 38 - 44
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