A Rare-Earth Metal Variant of the Tebbe Reagent

被引：94

作者：

Litlabo, Rannveig ^{[1
]}

Zimmermann, Melanie ^{[1
]}

Saliu, Kuburat ^{[2
]}

Takats, Josef ^{[2
]}

Tornroos, Karl W. ^{[1
]}

Anwander, Reiner ^{[1
]}

机构：

[1] Univ Bergen, Dept Chem, N-5007 Bergen, Norway

[2] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 49期

基金：

加拿大自然科学与工程研究理事会;

关键词：

aluminum; lanthanides; rare-earth metals; scorpionate ligands; Tebbe reagent;

D O I：

10.1002/anie.200803856

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) The Trofimenko-Tebbe alliance: The sterically crowded, monoanionic scorpionate ligand TptBu,Me provides a unique environment for the isolation of discrete rare-earth metal complexes with Y-(CH3){Al(CH3)4} and La-(CH2) moieties (see structure; C gray, H white, Al orange, B red, La pink, N blue); the latter shows promising reactivity as a Tebbe reagent analogue. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9560 / 9564

页数：5

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