Electron spin catalysis

被引:144
作者
Buchachenko, AL [1 ]
Berdinsky, VL [1 ]
机构
[1] Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia
关键词
D O I
10.1021/cr010370l
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Spin catalysis was proved to operate in radical recombination, biradical decay, cis-trans isomerization of molecules, low-temperature recombination of spin-aligned hydrogen atoms, spin conversion of positronium atom, primary light-harvesting reactions in photosynthetic centers, paramagnetic quenching of excited molecules among others. Possibly the extent of the phenomenon may be larger than the level of current knowledge. As a driving force of spin conversion in triads, the exchange interaction competes with magnetic interactions in the pairs of spin carriers.
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页码:603 / 612
页数:10
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