Na2SO4-assisted synthesis of hexagonal-phase WO3 nanosheet assemblies with applicable electrochromic and adsorption properties

被引：91
作者：
Xiao, Wei [1 ]
Liu, Wenting [1 ]
Mao, Xuhui [1 ]
Zhu, Hua [1 ]
Wang, Dihua [1 ,2 ]
机构：
[1] Wuhan Univ, Sch Resource & Environm Sci, Wuhan 430072, Peoples R China
[2] Chinese Acad Sci, Inst Met Res, State Key Lab Corros & Protect, Shenyang 110016, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2013年 / 1卷 / 04期
关键词：
TUNGSTEN-OXIDE; THIN-FILMS; NANORODS; DEVICES; TRIOXIDE; NANOPARTICLES; DEPOSITION; CONVERSION; PROGRESS; SYSTEMS;
D O I：
10.1039/c2ta00545j
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
For the first time, a mesoporous hexagonal-phase Na0.17WO3.085.0.29H(2)O nanosheet/microflower hierarchical structure has been synthesized employing a one-pot hydrothermal process with the assistance of Na2SO4. It is shown that Na2SO4 not only acts as a stabilizer to facilitate the generation of a metastable hexagonal phase, but also function as a structure directing agent to assist the construction of nanosheet assemblies. The formation mechanisms have been rationalized. The materials have been thoroughly characterized by XRD/BET/FESEM/EDX/TEM/TGA. This hexagonal-phase Na0.17WO3.085.0.29H(2)O nanosheet/microflower hierarchical structure exhibits applicable electrochromic and adsorptive properties due to its unique crystallographic configuration and microstructures, promising its application in energy-saving smart windows and wastewater treatment.
引用
收藏
页码：1261 / 1269
页数：9
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