Na2SO4-assisted synthesis of hexagonal-phase WO3 nanosheet assemblies with applicable electrochromic and adsorption properties

被引：93

作者：

Xiao, Wei ^{[1
]}

Liu, Wenting ^{[1
]}

Mao, Xuhui ^{[1
]}

Zhu, Hua ^{[1
]}

Wang, Dihua ^{[1
,2
]}

机构：

[1] Wuhan Univ, Sch Resource & Environm Sci, Wuhan 430072, Peoples R China

[2] Chinese Acad Sci, Inst Met Res, State Key Lab Corros & Protect, Shenyang 110016, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2013年 / 1卷 / 04期

关键词：

TUNGSTEN-OXIDE; THIN-FILMS; NANORODS; DEVICES; TRIOXIDE; NANOPARTICLES; DEPOSITION; CONVERSION; PROGRESS; SYSTEMS;

D O I：

10.1039/c2ta00545j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

For the first time, a mesoporous hexagonal-phase Na0.17WO3.085.0.29H(2)O nanosheet/microflower hierarchical structure has been synthesized employing a one-pot hydrothermal process with the assistance of Na2SO4. It is shown that Na2SO4 not only acts as a stabilizer to facilitate the generation of a metastable hexagonal phase, but also function as a structure directing agent to assist the construction of nanosheet assemblies. The formation mechanisms have been rationalized. The materials have been thoroughly characterized by XRD/BET/FESEM/EDX/TEM/TGA. This hexagonal-phase Na0.17WO3.085.0.29H(2)O nanosheet/microflower hierarchical structure exhibits applicable electrochromic and adsorptive properties due to its unique crystallographic configuration and microstructures, promising its application in energy-saving smart windows and wastewater treatment.

引用

页码：1261 / 1269

页数：9

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