Ferromagnetic order in a μ-cyano CrIII-MnII assembly with an unusual branched architecture

被引:48
作者
Marvilliers, A
Parsons, S
Rivière, E
Audière, JP
Mallah, T [1 ]
机构
[1] Univ Paris 11, Chim Inorgan Lab, CNRS, UMR 8613, F-91405 Orsay, France
[2] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
关键词
D O I
10.1039/a905191k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reacting hexacyanochromate(III) with a mononuclear Mn(II) complex chelated by a tetradentate ligand that leaves two coordination sites available in cis position leads to a new molecular ferromagnet (T-C = 17 K) with an unusual architecture.
引用
收藏
页码:2217 / 2218
页数:2
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