Remote sp2 C-H Carboxylation via Catalytic 1,4-Ni Migration with CO2

被引：60

作者：

Boerjesson, Marino ^{[1
]}

Janssen-Mueller, Daniel ^{[1
]}

Sahoo, Basudev ^{[1
]}

Duan, Yaya ^{[1
]}

Wang, Xueqiang ^{[1
]}

Martin, Ruben ^{[1
,2
]}

机构：

[1] Barcelona Inst Sci & Technol, Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

[2] ICREA, Barcelona 08010, Spain

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2020年 / 142卷 / 38期

基金：

欧盟地平线“2020”;

关键词：

CROSS-COUPLING REACTIONS; ARYLZINC REAGENTS; CARBON-DIOXIDE; ARYLATIVE CYCLIZATION; ALKYL-HALIDES; BOND; PALLADIUM; RHODIUM; ACTIVATION; 1,3-ENYNES;

D O I：

10.1021/jacs.0c08810

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A remote catalytic reductive sp(2.) C-H carboxylation of arenes with CO2 (1 bar) via 1,4-Ni migration is disclosed. This protocol constitutes the first catalytic 1,4-Ni migration reported to date, thus offering new vistas in the Ni-catalyzed reductive coupling arena while providing an unconventional new platform for incorporating electrophilic sites at remote sp(2) C-H linkages.

引用

页码：16234 / 16239

页数：6

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