Two new compounds constructed from polyoxoanions, metal ions and organic ligands

被引：5
作者：
Shi, Shu-Yun [1 ]
Xu, Zhan-Lin [1 ]
Teng, Hong-Hui [1 ]
Zhao, Ling-Zi [1 ]
Cui, Xiao-Bing [2 ,3 ]
Xu, Ji-Qing [2 ,3 ]
机构：
[1] Jilin Normal Univ, Coll Environm Engn, Siping 136000, Peoples R China
[2] Jilin Univ, Dept Chem, Coll Chem, Changchun 130023, Peoples R China
[3] Jilin Univ, Dept Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2013年 / 402卷
基金：
中国国家自然科学基金;
关键词：
Hydrothermal synthesis; POMMOF compounds; Structure; Characterization; HYDROTHERMAL SYNTHESIS; STRUCTURAL-CHARACTERIZATION; POLYOXOMETALATE CLUSTERS; 2-DIMENSIONAL FRAMEWORK; COMPLEX; POLYMER; SERIES; ARCHITECTURES; CHEMISTRY; SOLIDS;
D O I：
10.1016/j.ica.2013.03.031
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new compounds, namely [Cu-4(4,4'-bpy)(4)][SiW12O40]center dot 6H(2)O (1) and [Cu-2(4,4'-bpy)(2)][SiMo12O40]center dot(H(2)4,4'-bpy) (2) (bpy = bipyridine), have been hydrothermally synthesized and characterized by IR, UV-Vis, X-ray photoelectron spectroscopy (XPS), powder XRD, elemental analyses and single crystal X-ray diffraction. The two compounds represent new examples of compounds constructed from Keggin polyanions, metal ions and organic ligands. Compounds 1 and 2 both contains Cu(4,4'-bpy)(n)(n+) infinite chains and [SiM12O40](4) anions (M = W for 1 and M = Mo for 2). However, the structures of compounds 1 and 2 are thoroughly different. The Cu(4,4'-bpy)(n)(n+) infinite chains and [SiW12O40](4) anions in compound 1 are connected into a 2-D layered framework structure, and the Cu(4,4'-bpy)(n)(n+) infinite chains and [SiMo12O40](4) anions in compound 2 are linked into a 1-D ladder-like structure. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：123 / 127
页数：5
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