Luminescent Neutral Platinum Complexes Bearing an Asymmetric N∧N∧N Ligand for High-Performance Solution-Processed OLEDs

被引：94

作者：

Cebrian, Cristina ^{[1
,2
]}

Mauro, Matteo ^{[1
,2
]}

Kourkoulos, Dimitrios ^{[3
]}

Mercandelli, Pierluigi ^{[4
]}

Hertel, Dirk ^{[3
]}

Meerholz, Klaus ^{[3
]}

Strassert, Cristian A. ^{[1
,2
]}

De Cola, Luisa ^{[1
,2
]}

机构：

[1] Univ Munster, Inst Phys, D-48149 Munster, Germany

[2] Univ Munster, Ctr Nanotechnol CeNTech, D-48149 Munster, Germany

[3] Univ Cologne, Dept Chem, D-50939 Cologne, Germany

[4] Univ Milan, Dept Chem, I-20133 Milan, Italy

来源：

ADVANCED MATERIALS | 2013年 / 25卷 / 03期

关键词：

platinum complexes; tridentate ligand; asymmetric; luminescence; OLED; PT(II) COMPLEXES; PHOTOPHYSICS; PHOSPHORESCENCE; EFFICIENCY; EMISSION; CRYSTALS; PI;

D O I：

10.1002/adma.201202123

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and full characterization of new platinum complexes bearing a bulky asymmetric dianionic tridentate ligand is reported. The hindrance of the ligand prevents detrimental intermolecular interactions yielding to highly emitting species in both crystalline state and thin-film. Such properties prompted their successful use in solution-processed OLEDs, showing remarkable external quantum efficiency up to 5.6%. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：437 / 442

页数：6

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