Dielectric, pyroelectric and piezoelectric properties in the (1-x)(0.1BaTiO3-0.9NaNbO3)-xLiNbO3 system

被引:1
作者
Benabdallah, F. [1 ,2 ]
Aydi, A. [1 ]
Abdelmoula, N. [1 ]
Khemakhem, H. [1 ]
Simon, A. [2 ]
Von Der Muehll, R. [2 ]
Maglione, M. [2 ]
机构
[1] Univ Sfax, Lab Mat Ferroelect, UR 05 UR 15 04, Fac Sci Sfax, Sfax 3000, Tunisia
[2] Univ Bordeaux, CNRS, ICMCB, F-33608 Pessac, France
关键词
Dielectric; Pyroelectric; Piezoelectric; LEAD-FREE PIEZOCERAMICS; CERAMICS; TRANSITION;
D O I
10.1016/j.solidstatesciences.2012.07.010
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
New lead free piezoceramics with the given compositions (1 - x)(0.1BaTiO(3)-0.9NaNbO(3))-xLiNbO(3) (0.01 <= x <= 0.125) were prepared by solid-state reaction technique. XRD patterns revealed a single perovskite-structured phase only for 0.01 <= x <= 0.05. The dielectric, pyroelectric and piezoelectric responses were investigated for compositions with x = 0.01 and 0.02. For both compositions, epsilon'(r) exhibited a sharp peak with no frequency dependence (classical ferroelectrics). Losses displayed a strong dispersion at low frequencies in the paraelectric phase which was attributed to Li ionic conductivity in these compositions. The spontaneous polarization was found to be 35 and approximate to 22 mu C cm(-2) for x = 0.01 and 0.02 respectively. The transverse piezoelectric coefficient d(31) measured for x = 0.01 reached value of 37 pC/N at room temperature while the planar coupling factor was about 0.23. (C) 2012 Elsevier Masson SAS. All rights reserved.
引用
收藏
页码:1333 / 1337
页数:5
相关论文
共 21 条
[1]  
Abdelkafi Z., 2008, PHYS STATUS SOLIDI A, P1
[3]   Linking large piezoelectric coefficients to highly flexible polarization of lead free BaTiO3-CaTiO3-BaZrO3 ceramics [J].
Benabdallah, F. ;
Simon, A. ;
Khemakhem, H. ;
Elissalde, C. ;
Maglione, M. .
JOURNAL OF APPLIED PHYSICS, 2011, 109 (12)
[4]   Frustration of tilts and A-site driven ferroelectricity in KNbO3-LiNbO3 alloys [J].
Bilc, DI ;
Singh, DJ .
PHYSICAL REVIEW LETTERS, 2006, 96 (14)
[5]   Preparation and characterization of (K0.5Na0.5)NbO3 ceramics [J].
Birol, H ;
Damjanovic, D ;
Setter, N .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2006, 26 (06) :861-866
[6]   INVESTIGATION OF ELECTRICAL PROPERTIES OF SR1-XBAXNB2O6 WITH SPECIAL REFERENCE TO PYROELECTRIC DETECTION [J].
GLASS, AM .
JOURNAL OF APPLIED PHYSICS, 1969, 40 (12) :4699-&
[7]   Phase-transition temperatures and piezoelectric properties of (Bi1/2Na1/2)TiO3-(Bi1/2Li1/2)TiO3-(Bi1/2K1/2)TiO3 lead-free ferroelectric ceramics [J].
Hiruma, Yuji ;
Nagata, Hajime ;
Takenaka, Tadashi .
IEEE TRANSACTIONS ON ULTRASONICS FERROELECTRICS AND FREQUENCY CONTROL, 2007, 54 (12) :2493-2499
[8]  
*IEEE ANSI, 1987, 176 IEEEANSI
[9]  
Khemakhem H., 2000, J PHYS CONDENS MATT
[10]   Phase transitions of sodium niobate powder and ceramics, prepared by solid state synthesis [J].
Koruza, J. ;
Tellier, J. ;
Malic, B. ;
Bobnar, V. ;
Kosec, M. .
JOURNAL OF APPLIED PHYSICS, 2010, 108 (11)