Half-metallocene-type ruthenium complexes as active catalysts for living radical polymerization of methyl methacrylate and styrene

被引:126
|
作者
Takahashi, H [1 ]
Ando, T [1 ]
Kamigaito, M [1 ]
Sawamoto, M [1 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Kyoto 6068501, Japan
关键词
D O I
10.1021/ma981798y
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The living radical polymerization of methyl methacrylate (MMA) and styrene in conjunction with organic halide initiators was achieved by using the indenyl complex Ru(Ind)Cl(PPh3)2. This polymerization process yielded very narrow molecular weight distributions (MWDs) and controlled molecular weights.
引用
收藏
页码:3820 / 3823
页数:4
相关论文
共 50 条
  • [21] Radical polymerization of methyl methacrylate and styrene in the presence of ferrocene
    Puzin, YI
    Yumagulova, RK
    Kraikin, VA
    EUROPEAN POLYMER JOURNAL, 2001, 37 (09) : 1801 - 1812
  • [22] (Allylbenzene)tricarbonylchromium in radical polymerization of methyl methacrylate and styrene
    Grishin, DF
    Valetova, NB
    Semenycheva, LL
    Il'ichev, IS
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2005, 78 (08) : 1325 - 1328
  • [23] Titanium alkoxides for the fast ruthenium-catalyzed living radical polymerization of methyl methacrylate
    Hamasaki, S
    Ando, T
    Kamigaito, M
    Sawamoto, M
    KOBUNSHI RONBUNSHU, 2004, 61 (04) : 256 - 262
  • [24] Design of initiators for living radical polymerization of methyl methacrylate mediated by ruthenium(II) complex
    Ando, T
    Kamigaito, M
    Sawamoto, M
    TETRAHEDRON, 1997, 53 (45) : 15445 - 15457
  • [25] Sulfonyl chlorides as initiators for the Ruthenium-mediated living radical polymerization of methyl methacrylate
    Matsuyama, Mutsuhiro
    Kamigaito, Masami
    Sawamoto, Mitsuo
    1996, John Wiley & Sons Inc, New York, NY, United States (34)
  • [26] Organostibine-Mediated Controlled/Living Radical Polymerization of Methyl Methacrylate and Styrene in Ionic Liquids
    Cui, Guoyou
    Li, Jun
    Liu, Zhengping
    Dou, Junyan
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2010, 211 (11) : 1222 - 1228
  • [27] Controlled/''living'' radical polymerization of methyl methacrylate by atom transfer radical polymerization
    Grimaud, T
    Matyjaszewski, K
    MACROMOLECULES, 1997, 30 (07) : 2216 - 2218
  • [28] EFFECT OF SOLVENTS ON THE RADICAL POLYMERIZATION OF METHYL-METHACRYLATE AND STYRENE
    MADRUGA, EL
    SANROMAN, J
    DELPUERTO, MA
    ANALES DE QUIMICA, 1979, 75 (04): : 294 - 299
  • [29] Polymerization of methyl methacrylate by metallocene imido complexes and tris(pentafluorophenyl)alane
    Jin, JZ
    Mariott, WR
    Chen, EYX
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (20) : 3132 - 3142
  • [30] "Living" Radical Polymerization of Styrene Catalyzed by Cyclometalated Ruthenium(II) Complexes Bearing Nonlabile Ligands
    Aguilar-Lugo, C.
    Le Lagadec, R.
    Ryabov, Alexander D.
    Cedillo Valverde, G.
    Lopez Morales, S.
    Alexandrova, L.
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (15) : 3814 - 3828