Half-metallocene-type ruthenium complexes as active catalysts for living radical polymerization of methyl methacrylate and styrene

被引:126
作者
Takahashi, H [1 ]
Ando, T [1 ]
Kamigaito, M [1 ]
Sawamoto, M [1 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Kyoto 6068501, Japan
关键词
D O I
10.1021/ma981798y
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The living radical polymerization of methyl methacrylate (MMA) and styrene in conjunction with organic halide initiators was achieved by using the indenyl complex Ru(Ind)Cl(PPh3)2. This polymerization process yielded very narrow molecular weight distributions (MWDs) and controlled molecular weights.
引用
收藏
页码:3820 / 3823
页数:4
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