Half-metallocene-type ruthenium complexes as active catalysts for living radical polymerization of methyl methacrylate and styrene

被引:126
|
作者
Takahashi, H [1 ]
Ando, T [1 ]
Kamigaito, M [1 ]
Sawamoto, M [1 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Kyoto 6068501, Japan
关键词
D O I
10.1021/ma981798y
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The living radical polymerization of methyl methacrylate (MMA) and styrene in conjunction with organic halide initiators was achieved by using the indenyl complex Ru(Ind)Cl(PPh3)2. This polymerization process yielded very narrow molecular weight distributions (MWDs) and controlled molecular weights.
引用
收藏
页码:3820 / 3823
页数:4
相关论文
共 50 条
  • [1] Half-metallocene-type ruthenium complexes as active catalysts for living radical polymerization of methyl methacrylate and styrene
    Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 606-8501, Japan
    Macromolecules, 11 (3820-3823):
  • [2] Radical polymerization of styrene and methyl methacrylate with Ruthenium(II) complexes
    Arrowood, BN
    Lail, M
    Gunnoe, TB
    Boyle, PD
    ORGANOMETALLICS, 2003, 22 (23) : 4692 - 4698
  • [3] Living radical polymerization of styrene by half-metallocene iron carbonyl complexes
    Kotani, Y
    Kamigaito, M
    Sawamoto, M
    MACROMOLECULES, 2000, 33 (10) : 3543 - 3549
  • [4] Specifics of radical polymerization of styrene and methyl methacrylate in the presence of ruthenium carborane complexes
    Grishin, I. D.
    Kolyakina, E. V.
    Cheredilin, D. N.
    Chizhevskii, I. T.
    Grishin, D. F.
    POLYMER SCIENCE SERIES A, 2007, 49 (10) : 1079 - 1085
  • [5] Specifics of radical polymerization of styrene and methyl methacrylate in the presence of ruthenium carborane complexes
    I. D. Grishin
    E. V. Kolyakina
    D. N. Cheredilin
    I. T. Chizhevskii
    D. F. Grishin
    Polymer Science Series A, 2007, 49 : 1079 - 1085
  • [6] FeCp(CO)2I:: A phosphine-free half-metallocene-type iron(II) catalyst for living radical polymerization of styrene
    Kotani, Y
    Kamigaito, M
    Sawamoto, M
    MACROMOLECULES, 1999, 32 (20) : 6877 - 6880
  • [7] Controlled/"living" radical polymerization of styrene and methyl methacrylate catalyzed by iron complexes
    Matyjaszewski, K
    Wei, ML
    Xia, JH
    McDermott, NE
    MACROMOLECULES, 1997, 30 (26) : 8161 - 8164
  • [8] Highly Active Half-Metallocene Yttrium Catalysts for Living and Chemoselective Polymerization of Allyl Methacrylate
    Xu, Tieqi
    Liu, Junhu
    Lu, Xiao-Bing
    MACROMOLECULES, 2015, 48 (20) : 7428 - 7434
  • [9] Iron Oxides as Heterogeneous Catalysts for Controlled/Living Radical Polymerization of Styrene and Methyl Methacrylate
    Kanazawa, Arihiro
    Satoh, Kotaro
    Kamigaito, Masami
    MACROMOLECULES, 2011, 44 (07) : 1927 - 1933
  • [10] Ruthenium carborane complexes in the controlled radical polymerization of methyl methacrylate
    E. V. Kolyakina
    I. D. Grishin
    D. N. Cheredilin
    F. M. Dolgushin
    I. T. Chizhevsky
    D. F. Grishin
    Russian Chemical Bulletin, 2006, 55 : 89 - 93