An overview of the 2013 Las Vegas Ozone Study (LVOS): Impact of stratospheric intrusions and long-range transport on surface air quality

被引:77
作者
Langford, A. O. [1 ]
Senff, C. J. [1 ,2 ]
Alvarez, R. J., II [1 ]
Brioude, J. [1 ,2 ,3 ]
Cooper, O. R. [1 ,2 ]
Holloway, J. S. [1 ,2 ]
Lin, M. Y. [4 ,5 ]
Marchbanks, R. D. [1 ,2 ]
Pierce, R. B. [6 ]
Sandberg, S. P. [1 ]
Weickmann, A. M. [1 ,2 ]
Williams, E. J. [1 ]
机构
[1] NOAA, Earth Syst Res Lab, Div Chem Sci, Boulder, CO 80305 USA
[2] Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA
[3] UMR 8105, Lab Atmosphere & Cyclones LACy, St Denis, Reunion, France
[4] Princeton Univ, Atmospher & Ocean Sci, Princeton, NJ 08544 USA
[5] NOAA, Geophys Fluid Dynam Lab, Princeton, NJ USA
[6] NOAA, NESDIS, Ctr Satellite Applicat & Res, Cooperat Inst Meteorol Satellite Studies, Madison, WI 53706 USA
关键词
Background ozone; Stratosphere-to-troposphere transport; Long range transport; Asian pollution; Surface ozone; NAAQS; Exceedances; CARBON-MONOXIDE; UNITED-STATES; TROPOSPHERIC TRANSPORT; BACKGROUND OZONE; EMISSIONS; POLLUTION; MODEL; SITES; FIRES;
D O I
10.1016/j.atmosenv.2014.08.040
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The 2013 Las Vegas Ozone Study (LVOS) was conducted in the late spring and early summer of 2013 to assess the seasonal contribution of stratosphere-to-troposphere transport (SIT) and long-range transport to surface ozone in Clark County, Nevada and determine if these processes directly contribute to exceedances of the National Ambient Air Quality Standard (NAAQS) in this area. Secondary goals included the characterization of local ozone production, regional transport from the Los Angeles Basin, and impacts from wildfires. The LVOS measurement campaign took place at a former U.S. Air Force radar station similar to 45 km northwest of Las Vegas on Angel Peak (similar to 2.7 km above mean sea level, asl) in the Spring Mountains. The study consisted of two extended periods (May 19-June 4 and June 22-28, 2013) with near daily 5-min averaged lidar measurements of ozone and backscatter profiles from the surface to similar to 2.5 km above ground level (similar to 5.2 km asl), and continuous in situ measurements (May 20-June 28) of O-3, CO, (1-min) and meteorological parameters (5-min) at the surface. These activities were guided by forecasts and analyses from the FLEXPART (FLEXible PARTticle) dispersion model and the Real Time Air Quality Modeling System (RAQMS), and the NOAA Geophysical Research Laboratory (NOAA GFDL) AM3 chemistry-climate model. In this paper, we describe the LVOS measurements and present an overview of the results. The combined measurements and model analyses show that STT directly contributed to each of the three O-3 exceedances that occurred in Clark County during LVOS, with contributions to 8-h surface concentrations in excess of 30 ppbv on each of these days. The analyses show that long-range transport from Asia made smaller contributions (<10 ppbv) to surface O-3 during two of those exceedances. The contribution of regional wildfires to surface O-3 during the three LVOS exceedance events was found to be negligible, but wildfires were found to be a major factor during exceedance events that occurred before and after the LVOS campaign. Our analyses also shows that ozone exceedances would have occurred on more than 50% of the days during the six-week LVOS campaign if the 8-h ozone NAAQS had been 65 ppbv instead of 75 ppbv. Published by Elsevier Ltd.
引用
收藏
页码:305 / 322
页数:18
相关论文
共 59 条
[1]   Development and Application of a Compact, Tunable, Solid-State Airborne Ozone Lidar System for Boundary Layer Profiling [J].
Alvarez, R. J., II ;
Senff, C. J. ;
Langford, A. O. ;
Weickmann, A. M. ;
Law, D. C. ;
Machol, J. L. ;
Merritt, D. A. ;
Marchbanks, R. D. ;
Sandberg, S. P. ;
Brewer, W. A. ;
Hardesty, R. M. ;
Banta, R. M. .
JOURNAL OF ATMOSPHERIC AND OCEANIC TECHNOLOGY, 2011, 28 (10) :1258-1272
[2]   Causes of high O3 in the lower free troposphere over the Pacific Northwest as observed at the Mt. Bachelor Observatory [J].
Ambrose, J. L. ;
Reidmiller, D. R. ;
Jaffe, D. A. .
ATMOSPHERIC ENVIRONMENT, 2011, 45 (30) :5302-5315
[3]  
[Anonymous], 2012, OUR NAT AIR STAT TRE
[4]   Mixing between a stratospheric intrusion and a biomass burning plume [J].
Brioude, J. ;
Cooper, O. R. ;
Trainer, M. ;
Ryerson, T. B. ;
Holloway, J. S. ;
Baynard, T. ;
Peischl, J. ;
Warneke, C. ;
Neuman, J. A. ;
De Gouw, J. ;
Stohl, A. ;
Eckhardt, S. ;
Frost, G. J. ;
McKeen, S. A. ;
Hsie, E.-Y. ;
Fehsenfeld, F. C. ;
Nedelec, P. .
ATMOSPHERIC CHEMISTRY AND PHYSICS, 2007, 7 (16) :4229-4235
[5]   Effect of biomass burning on marine stratocumulus clouds off the California coast [J].
Brioude, J. ;
Cooper, O. R. ;
Feingold, G. ;
Trainer, M. ;
Freitas, S. R. ;
Kowal, D. ;
Ayers, J. K. ;
Prins, E. ;
Minnis, P. ;
McKeen, S. A. ;
Frost, G. J. ;
Hsie, E. -Y. .
ATMOSPHERIC CHEMISTRY AND PHYSICS, 2009, 9 (22) :8841-8856
[6]   Asian influence on surface ozone in the United States: A comparison of chemistry, seasonality, and transport mechanisms [J].
Brown-Steiner, Benjamin ;
Hess, Peter .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2011, 116
[7]   Response of ozone and nitrate to stationary source NOx emission reductions in the eastern USA [J].
Butler, Thomas J. ;
Vermeylen, Francoise M. ;
Rury, Melissa ;
Likens, Gene E. ;
Lee, Brian ;
Bowker, George E. ;
McCluney, Lance .
ATMOSPHERIC ENVIRONMENT, 2011, 45 (05) :1084-1094
[8]  
Cooper O.R., 2004, J. Geophys. Res, V109
[9]  
Cooper O. R., 2004, J GEOPHYS RES, V108
[10]   Long-term ozone trends at rural ozone monitoring sites across the United States, 1990-2010 [J].
Cooper, Owen R. ;
Gao, Ru-Shan ;
Tarasick, David ;
Leblanc, Thierry ;
Sweeney, Colm .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2012, 117