Syntheses and Structures of Two Metal organic Frameworks Constructed from Zn/Ni and 3-Formyl-4-(pyridin-4-yl) Benzoic Acid Ligand

被引：1

作者：

Abbas, Anees ^{[1
,2
]}

Zhang Jie ^{[1
,2
]}

Li Zi-Jian ^{[1
,2
]}

Liu Yan ^{[1
,2
]}

Liu Bai-Zhan ^{[3
]}

Cui Yong ^{[1
,2
]}

机构：

[1] Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China

[2] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China

[3] China Tobacco, Shanghai 200240, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 37卷 / 02期

基金：

中国国家自然科学基金;

关键词：

metal-organic frameworks; crystal structure; Zn; Ni; formyl; ASYMMETRIC CATALYSIS; MAGNETIC-PROPERTIES; COORDINATION; ADSORPTION; SEPARATION; LINKERS;

D O I：

10.14102/j.cnki.0254-5861.2011-1712

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two metal-organic frameworks [(Zn0.5L)center dot(H2O)](n) (1) and [Ni0.5L)center dot(H2O)] (2) constructed by the 3-formyl-4-(pyridin-4-yl) benzoic acid ligand (HL) were synthesized and characterized by single-crystal X-ray diffraction. 1 crystallizes in orthorhombic space group Pnna with a = 16.6152(8), b = 12.6825(6), c = 15.3908(8) angstrom, V = 3243.2(3) angstrom(3), Z = 4, M-r = 511.12, D-c = 1.047 g/cm(3), F(000) = 1048, mu = 1.144 mm(-1), GOOF = 1.061, the final R = 0.0471 and wR = 0.1262 for 12168 observed reflections with I > 2 sigma(I). 2 is isostructural to 1, which also crystallizes in orthorhombic space group Pnna with a = 16.6152(8), b = 12.6825(6), c = 15.3908(8) A, V = 3243.2(3) angstrom(3), Z = 4, M-r = 511.12, D-c= 1.047 g/cm(3), F(000) = 1048, mu = 1.144 mm(-1), GOOF = 1.061, the final R = 0.0471 and wR = 0.1262 for 12168 observed reflections with I > 2 sigma(I). Additionally, thermogravimetric analysis, FT-IR spectroscopy and powder X-ray diffraction were discussed.

引用

页码：292 / 298

页数：7

共 41 条

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