Light absorption and hole-transport properties of copper corroles: from aggregates to a liquid crystal mesophase

被引：9

作者：

Gao, Di ^{[1
]}

Edzang, Judicaelle Andeme ^{[2
]}

Diallo, Abdou Karim ^{[2
]}

Dutronc, Thibault ^{[3
]}

Balaban, Teodor Silviu ^{[1
]}

Videlot-Ackermann, Christine ^{[2
]}

Terazzi, Emmanuel ^{[3
]}

Canard, Gabriel ^{[2
]}

机构：

[1] Aix Marseille Univ, Cent Marseille, CNRS, iSm2 UMR 7313, F-13397 Marseille, France

[2] Aix Marseille Univ, CNRS, CINaM UMR 7325, F-13288 Marseille, France

[3] Univ Geneva, Dept Inorgan & Analyt Chem, CH-1211 Geneva 4, Switzerland

来源：

NEW JOURNAL OF CHEMISTRY | 2015年 / 39卷 / 09期

关键词：

FRACTURE ELECTRON-MICROSCOPY; REDUCTIVE DEMETALATION; MESO-TRIARYLCORROLES; CELLULAR UPTAKE; FUNCTIONALIZATION; PHTHALOCYANINES; PORPHYRINS; COLUMNAR; FILM; NANOPARTICLES;

D O I：

10.1039/c5nj01268f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of the corroLe-based Liquid crystaL phase CorLC is described together with its fuLL characterization using a combination of PoLarised OpticaL Microscopy (DOM), ThermoGravimetric AnaLysis (TGA), DifferentiaL Scanning CaLorimetry (DSC) measurements and SmaLL-AngLe X-Ray Diffraction (SA-XRD), which shows that CorLC has a hexagonaL coLumnar organization at room temperature. The Light absorption and hoLe-transport properties of the mesophase CorLC are compared with those featured by assembLies of its parent meso-triaryL (Cod) and per-aryL (Cor2) derivatives. J-Aggregates are repLaced by H-aggregates when the intermoLecuLar distance is increased by a higher peripheraL steric hindrance producing Lower hoLe-transport mobiLities.

引用

页码：7140 / 7146

页数：7

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