Thermogravimetric study of the combustion of Tetraselmis suecica microalgae and its blend with a Victorian brown coal in O2/N2 and O2/CO2 atmospheres

被引:95
作者
Tahmasebi, Arash [1 ]
Kassim, Mohd Asyraf [3 ]
Yu, Jianglong [1 ,2 ]
Bhattacharya, Sankar [3 ]
机构
[1] Univ Sci & Technol Liaoning, Key Lab Adv Coal & Coking Technol Liaoning Prov, Sch Chem Engn, Anshan 114051, Peoples R China
[2] Shenyang Aerosp Univ, Thermal Energy Res Ctr, Shenyang 110136, Peoples R China
[3] Monash Univ, Dept Chem Engn, Clayton, Vic 3150, Australia
基金
中国国家自然科学基金;
关键词
Microalgae; Brown coal; Co-combustion; Thermogravimetric analysis; Synergy; OXY-FUEL COMBUSTION; MARINE MICROALGAE; PYROLYSIS; BIOMASS; KINETICS; COCOMBUSTION; BEHAVIOR; GASIFICATION; ENERGY; ALGAE;
D O I
10.1016/j.biortech.2013.09.113
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
The combustion characteristics of microalgae, brown coal and their blends under O-2/N-2 and O-2/CO2 atmospheres were studied using thermogravimetry. In microalgae combustion, two peaks at 265 and 485 degrees C were attributable to combustion of protein and carbohydrate with lipid, respectively. The DIG profile of coal showed one peak with maximum mass loss rate at 360 degrees C. Replacement of N-2 by CO2 delayed the combustion of coal and microalgae. The increase in O-2 concentration did not show any effect on combustion of protein at the first stage of microalgae combustion. However, between 400 and 600 degrees C, with the increase of O-2 partial pressure the mass loss rate of microalgae increased and TG and DTG curves of brown coal combustion shifted to lower temperature zone. The lowest and highest activation energy values were obtained for coal and microalgae, respectively. With increased microalgae/coal ratio in the blends, the activation energy increased due to synergy effect. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:15 / 27
页数:13
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