Metal-Catalyzed Cross-Coupling Reactions for Ferrocene Functionalization: Recent Applications in Synthesis, Material Science and Asymmetric Catalysis

被引：32
作者：
Mamane, V. [1 ]
机构：
[1] Nancy Univ, Fac Sci & Tech, UMR CNRS UHP 7565, Equipe Organomet & React,Lab SRSMC, F-54506 Vandoeuvre Les Nancy, France
来源：
MINI-REVIEWS IN ORGANIC CHEMISTRY | 2008年 / 5卷 / 04期
关键词：
Cross-coupling; palladium; ferrocene; material chemistry; asymmetric catalysis;
D O I：
10.2174/157019308786242160
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Recent examples on the functionalization of the ferrocene core by means of cross-coupling reactions are reported in this review. Several methods are discussed including Negishi, Suzuki and Stille couplings for ferrocene-aryl bond formation and Sonogashira reaction for ferrocene-alkyne coupling. The properties in material science and asymmetric catalysis of the prepared ferrocenyl compounds are briefly discussed.
引用
收藏
页码：303 / 312
页数：10
相关论文
共 81 条
  • [21] Metallocene sulfoxides as precursors of metallocenes with planar chirality
    Ferber, Benoit
    Kagan, Henri B.
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (4-5) : 493 - 507
  • [22] Synthesis of optically pure o-formylcyclopentadienyl metal complexes of 17α-ethynylestradiol.: Recognition of the planar chirality by the estrogen receptor
    Ferber, Benoit
    Top, Siden
    Vessieres, Anne
    Welter, Richard
    Jaouen, Gerard
    [J]. ORGANOMETALLICS, 2006, 25 (24) : 5730 - 5739
  • [23] A new phthalocyanine-ferrocene conjugated dyad
    González-Cabello, A
    Vázquez, P
    Torres, T
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 637 : 751 - 756
  • [24] HIGH-YIELD SYNTHESIS OF MONOSUBSTITUTED FERROCENES
    GUILLANEUX, D
    KAGAN, HB
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (08) : 2502 - 2505
  • [25] Hayashi T., 1995, FERROCENES
  • [26] Main chain ferrocenyl amides from 1-aminoferrocene-1′-carboxylic acid
    Heinze, K
    Schlenker, M
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (14) : 2974 - 2988
  • [27] HELBERG FL, 1969, TETRAHEDRON LETT, V10, P4011
  • [28] Communication between Co2(CO)4dppm units via polyferrocenylalkyne linkages
    Hore, LA
    McAdam, CJ
    Kerr, JL
    Duffy, NW
    Robinson, BH
    Simpson, J
    [J]. ORGANOMETALLICS, 2000, 19 (24) : 5039 - 5048
  • [29] Metal-centered ferrocene clusters from 5-ferrocenylpyrimidine and ferrocenylpyrazine
    Horikoshi, R
    Nambu, C
    Mochida, T
    [J]. INORGANIC CHEMISTRY, 2003, 42 (21) : 6868 - 6875
  • [30] Parallel and perpendicular stacking of ferrocene rings.: Syntheses, X-ray structures, and electrochemistry of 1,8-bis-[1-(1′-phenylthio)ferrocenyl] naphthalene and 8,8′-bis-[1-(1′-phenylthio)ferrocenyl]-1,1′-binaphthyl
    Hua, DH
    McGill, JW
    Lou, K
    Ueki, A
    Helfrich, B
    Desper, J
    Zanello, P
    Cinquantini, A
    Corsini, M
    Fontani, M
    [J]. INORGANICA CHIMICA ACTA, 2003, 350 : 259 - 265
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