Designed Synthesis of SiO2/TiO2 Core/Shell Structure As Light Scattering Material for Highly Efficient Dye-Sensitized Solar Cells

被引:171
作者
Son, Suim [1 ]
Hwang, Sun Hye [1 ]
Kim, Chanhoi [1 ]
Yun, Ju Young [1 ]
Jang, Jyongsik [1 ]
机构
[1] Seoul Natl Univ, World Class Univ WCU, Program Chem Convergence Energy & Environm C2E2, Sch Chem & Biol Engn, Seoul 151742, South Korea
基金
新加坡国家研究基金会;
关键词
SiO2/TiO2 core/shell nanoparticle; light scattering; Mie scattering; dye-sensitized solar cell; TIO2; BEADS; SIMULATIONS;
D O I
10.1021/am400441v
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
SiO2/TiO2 core/shell nanoparticles (STCS-NPs) with diameters of 110, 240, and 530 nm were fabricated to investigate the influence of the size and refractive index of light-scattering particles on light-scattering properties. The optical properties of STCS-NPs were evaluated and compared with SiO2-NPs and TiO2-NPs. The structure of STCS-NPs, consisting of a low refractive index core and high refractive index shell, provides efficient light scattering. The optimized anode film with STCS-NPs had ca. 20% improved power conversion efficiency (PCE).
引用
收藏
页码:4815 / 4820
页数:6
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