Near-infrared photothermal conversion of stable radicals photoinduced from a viologen-based coordination polymer

被引：59

作者：

Wang, Shanshan ^{[1
]}

Li, Shuning ^{[1
]}

Xiong, Junyu ^{[1
]}

Lin, Zhengguo ^{[1
]}

Wei, Wei ^{[2
]}

Xu, Yanqing ^{[1
]}

机构：

[1] Beijing Inst Technol, Sch Chem & Chem Engn, Beijing Key Lab Photoelect Electrophoton Convers, Key Lab Cluster Sci,Minist Educ China, Beijing 100081, Peoples R China

[2] Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 54期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORKS; PHOTOCHROMIC PROPERTIES; NANOPARTICLES; CRYSTALLINE; FLUORESCENT; COMPLEXES; DESIGN; LIGAND;

D O I：

10.1039/d0cc02193h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Upon simple UV-visible irradiation, a viologen-based coordination polymer was transformed to a highly stable radical, protected against quenching by a densely packed structure. The photo-generated radical exhibited a remarkable near-infrared (NIR) photo-thermal effect with good recyclability and high conversion efficiency. To our knowledge, this is the first example of a crystalline viologen-based coordination polymer that functions as a NIR photo-thermal material by forming stable radicals.

引用

页码：7399 / 7402

页数：4

共 55 条

[1] Highly Stable Organic Bisradicals Protected by Mechanical Bonds [J].

Cai, Kang ;

Mao, Haochuan ;

Liu, Wei-Guang ;

Qiu, Yunyan ;

Shi, Yi ;

Zhang, Long ;

Shen, Dengke ;

Chen, Hongliang ;

Jiao, Yang ;

Wu, Huang ;

Liu, Zhichang ;

Feng, Yuanning ;

Stern, Charlotte L. ;

Wasielewski, Michael R. ;

Goddard, William A., III ;

Stoddart, J. Fraser .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (15) :7190-7197

[2] Molecular Russian dolls [J].

Cai, Kang ;

Lipke, Mark C. ;

Liu, Zhichang ;

Nelson, Jordan ;

Cheng, Tao ;

Shi, Yi ;

Cheng, Chuyang ;

Shen, Dengke ;

Han, Ji-Min ;

Vemuri, Suneal ;

Feng, Yuanning ;

Stern, Charlotte L. ;

Goddard, William A., III ;

Wasielewski, Michael R. ;

Stoddart, J. Fraser .

NATURE COMMUNICATIONS, 2018, 9

[3] Flexible Viologen-Based Porous Framework Showing X-ray Induced Photochromism with Single-Crystal-to-Single-Crystal Transformation [J].

Chen, Cheng ;

Sun, Jian-Ke ;

Zhang, Ya-Jun ;

Yang, Xiao-Dong ;

Zhang, Jie .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (46) :14458-14462

[4] Photo- and thermo-activated electron transfer system based on a luminescent europium organic framework with spectral response from UV to visible range [J].

Chen, Hengjun ;

Zheng, Guiming ;

Li, Min ;

Wang, Yifang ;

Song, Yang ;

Han, Conghui ;

Dai, Jingcao ;

Fu, Zhiyong .

CHEMICAL COMMUNICATIONS, 2014, 50 (88) :13544-13546

[5] N-Methyl-4-pyridinium Tetrazolate Zwitterion-Based Photochromic Materials [J].

Chen, Xiang-Yi ;

Zhang, Ning-Ning ;

Cai, Li-Zhen ;

Li, Pei-Xin ;

Wang, Ming-Sheng ;

Guo, Guo-Cong .

CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (31) :7414-7417

[6] Distinct Chromic and Magnetic Properties of Metal Organic Frameworks with a Redox Ligand [J].

Gong, Teng ;

Yang, Xiao ;

Fang, Jia-Jia ;

Sui, Qi ;

Xi, Fu-Gui ;

Gao, En-Qing .

ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (06) :5503-5512

[7] Magnetic and Photochromic Properties of a Manganese(II) Metal-Zwitterionic Coordination Polymer [J].

Gong, Teng ;

Yang, Xiao ;

Sui, Qi ;

Qi, Yan ;

Xi, Fu-Gui ;

Gao, En-Qing .

INORGANIC CHEMISTRY, 2016, 55 (01) :96-103

[8] Fast detection of oxygen by the naked eye using a stable metal-organic framework containing methyl viologen cations [J].

Gong, Yun-Nan ;

Lu, Tong-Bu .

CHEMICAL COMMUNICATIONS, 2013, 49 (70) :7711-7713

[9] Crystalline and molecular design of functionalized viologens [J].

Gutov, A. V. ;

Rusanov, E. B. ;

Ryabitskii, A. B. ;

Tsimbal, I. F. ;

Chernega, A. N. .

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2009, 79 (09) :1910-1918

[10] Transparent Photothermal Heaters from a Soluble NIR-Absorbing Diimmonium Salt [J].

Han, Minsu ;

Kim, Byeonggwan ;

Lim, Hanwhuy ;

Jang, Hwandong ;

Kim, Eunkyoung .

ADVANCED MATERIALS, 2020, 32 (01)

← 1 2 3 4 5 6 →