Preparation and characterization of water soluble poly(acrylic acid)-hydroxypropyl cellulose composite

被引:25
作者
Abdel-Halim, E. S. [1 ]
Emam, H. E. [1 ]
El-Rafie, M. H. [1 ]
机构
[1] Natl Res Ctr, Text Res Div, Cairo, Egypt
关键词
polymerization; potassium bromate; thiourea; acrylic acid; hydroxypropyl cellulose; composite;
D O I
10.1016/j.carbpol.2008.04.037
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Purified flax waste was obtained from flax processing wastes via subjecting the latter to alkali treatment followed by peracetic acid bleaching. The so obtained purified flax wastes were chemically modified via reacting with propylene oxide in alkaline medium. The resultant hydroxypropyl cellulose (HPC) was incorporated in a polymerization medium containing acrylic acid and potassium bromate/thiourea mixture as initiation system. The polymerization reaction was monitored by determining the total conversion percent and the rheological properties of the resultant polyacrylic acid-hydroxypropyl cellulose composite [poly(AA)-HPC]. Results obtained indicate that the optimum conditions of polymerization process were: 12 mmole KBrO3, 4 mmole thiourea and 100 g acrylic acid/100 g HPC at 50 degrees C for 2 h using a material to liquor ratio of 1:5. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:783 / 786
页数:4
相关论文
共 16 条
[1]   Synthesis of chemically active polymeric fibers bearing sulfo and carboxy groups [J].
Bondar, Yu. V. ;
Lee, S. W. .
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2007, 80 (11) :1918-1922
[2]   New composite membranes based on crosslinked poly(acrylic acid) and porous polyethylene films [J].
Buyanov, A. L. ;
Revel'skaya, L. G. ;
Bobrova, N. V. ;
Elyashevich, G. K. .
POLYMER SCIENCE SERIES A, 2006, 48 (07) :738-744
[3]   Synthesis, characterization and metal ion sorption studies of graft copolymers of cellulose with glycidyl methacrylate and some comonomers [J].
Chauhan, GS ;
Guleria, L ;
Sharma, R .
CELLULOSE, 2005, 12 (01) :97-110
[4]  
El-Rafie M. H., 2007, Egyptian Journal of Textile and Polymer Sciences & Technology, V11, P197
[5]   Temperature-responsive cellulose by ceric(IV) ion-initiated graft copolymerization of N-isopropylacrylamide [J].
Gupta, KC ;
Khandekar, K .
BIOMACROMOLECULES, 2003, 4 (03) :758-765
[6]   Graft copolymerization of acrylic acid onto cellulose:: Effects of pretreatments and crosslinking agent [J].
Gürdag, G ;
Güçlü, G ;
Özgümüs, S .
JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 80 (12) :2267-2272
[7]  
KURATA M, 1975, POLYM HDB
[8]  
Lu J, 2001, J APPL POLYM SCI, V81, P3578
[9]   Interaction and scale of mixing in cellulose acetate/poly(N-vinyl pyrrolidone-co-vinyl acetate) blends [J].
Ohno, T ;
Yoshizawa, S ;
Miyashita, Y ;
Nishio, Y .
CELLULOSE, 2005, 12 (03) :281-291
[10]   Molecular relaxations in the composites of liquid crystalline cellulose derivatives with poly(acrylic acid) [J].
Okrasa, L ;
Boiteux, G ;
Ulanski, J ;
Seytre, G .
MATERIALS RESEARCH INNOVATIONS, 2001, 4 (5-6) :278-283