XPS and XRD study of FeCl3-graphite intercalation compounds prepared by arc discharge in aqueous solution

被引：41

作者：

Zhang Yan ^{[1
,2
]}

Zhang Zhuxia ^{[1
,2
]}

Li Tianbao ^{[1
,2
]}

Liu Xuguang ^{[1
,3
]}

Xu Bingshe ^{[1
,2
]}

机构：

[1] Taiyuan Univ Technol, Minist Educ, Key Lab Interface Sci & Engn Adv Mat, Taiyuan 030024, Peoples R China

[2] Taiyuan Univ Technol, Coll Mat Sci & Engn, Taiyuan 030024, Peoples R China

[3] Taiyuan Univ Technol, Coll Chem & Chem Engn, Taiyuan 030024, Peoples R China

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2008年 / 70卷 / 05期

关键词：

graphite; FeCl3; intercalation compounds; arc discharge;

D O I：

10.1016/j.saa.2007.10.031

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

A novel one-step synthesis method of FeCl3-graphite intercalation compounds (FeCl3-GICs) by an arc discharge in aqueous solution was reported for the first time. It presented a simply and controllable way to synthesize FeCl3-GICs. The structure of the stage 7 GICs was examined and characterized by X-ray diffraction. X-ray photoelectron spectroscopic study of stage 7 of FeCl3-GICs was also carried out. The change in the binding energy suggests the nature of charge transfer and lowering of Fermi level as has been reported previously for other acceptor intercalation compounds. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1060 / 1064

页数：5

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