Applications of surface-grafted macromolecules derived from post-polymerization modification reactions

被引：128
|
作者：
Galvin, Casey J. [1 ]
Genzer, Jan [1 ]
机构：
[1] N Carolina State Univ, Dept Chem & Biomol Engn, Raleigh, NC 27695 USA
来源：
PROGRESS IN POLYMER SCIENCE | 2012年 / 37卷 / 07期
基金：
美国国家科学基金会;
关键词：
Surface-anchored polymers; Post-polymerization modification; Polymer analogous reactions; Functional polymer layer; Polymer nanocomposites; Biomaterials; TRANSFER-RADICAL POLYMERIZATION; FRAGMENTATION CHAIN TRANSFER; MONOMER SEQUENCE DISTRIBUTIONS; SELF-ASSEMBLED MONOLAYERS; POLY(3-SULFOPROPYL METHACRYLATE) BRUSHES; SPHERICAL POLYELECTROLYTE BRUSHES; POLY(ACRYLIC ACID) BRUSHES; COPOLYMER FILMS; COVALENT IMMOBILIZATION; RESPONSIVE SURFACES;
D O I：
10.1016/j.progpolymsci.2011.12.001
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The formation of functional polymers by implementing small-molecule organic chemistry reactions to homopolymers has attracted great attention lately due to an increasing number of novel potential applications. This post-polymerization modification (PPM) approach circumvents a number of problems associated with direct polymer synthesis and enables the creation of polymeric systems that are difficult or impossible to produce otherwise. This holds especially true in the field of polymer brushes where the tethering of the polymer chains to a surface complicates direct polymerization of bulky monomers. The advantages of PPM reactions do not stop with polymer synthesis. This review highlights a variety of innovations that stem directly from this approach. A selection of these applications includes modified barrier properties, catalysis, surface patterning, separations, and biologically active substrates. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：871 / 906
页数：36
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