Quasi-Ternary System Ag2Se-CdSe-Ga2Se3

被引:1
作者
Kadykalo, E. M. [1 ]
Marushko, L. P. [1 ]
Zmiy, O. F. [1 ]
Olekseyuk, I. D. [1 ]
机构
[1] Lesya Ukrainka Eastern European Natl Univ, Dept Inorgan & Phys Chem, UA-43025 Lutsk, Ukraine
关键词
differential thermal analysis; invariant equilibria; isothermal section; liquidus surface; phase diagram; polythermal section; x-ray analysis; PHASE-DIAGRAM; CRYSTAL-STRUCTURE; CATION DISTRIBUTION; TEMPERATURE; EQUILIBRIA; AGCD2GAS4; COMPOUND; GROWTH; SE;
D O I
10.1007/s11669-013-0249-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Phase equilibria in the quasi-ternary system Ag2Se-CdSe-Ga2Se3 were investigated by differential thermal and x-ray phase analysis methods. Phase diagrams of nine vertical sections were constructed. The boundaries of seven single-phase fields were determined which are solid solution ranges of system components and intermediate phases. We constructed the isothermal section at 820 K and the liquidus surface projection, and have determined the position in the system of six invariant processes with the participation of liquid: (1145 K), (1138 K), (1113 K), (1083 K), (969 K), (963 K). Two invariant processes in the sub-solidus part, and at 968 and 938 K, respectively, were investigated as well.
引用
收藏
页码:403 / 415
页数:13
相关论文
共 50 条
[1]  
[Anonymous], 1966, IZV ACAD NAUK USSR N
[2]  
[Anonymous], 1975, SEMICONDUCTOR CHALCO
[3]  
[Anonymous], 1982, IAN SSSR NEORG MATER
[4]  
[Anonymous], 1987, IAN SSSR NEORG MATER
[5]  
[Anonymous], 2001, THESIS LVIV NATL U L
[6]   Structural and optical properties of noncentrosymmetric quaternary crystal AgCd2GaS4 [J].
Atuchin, V. V. ;
Pankevich, V. Z. ;
Parasyuk, O. V. ;
Pervukhina, N. V. ;
Pokrovsky, L. D. ;
Remesnik, V. G. ;
Uvarov, V. N. ;
Pekhnyo, V. I. .
JOURNAL OF CRYSTAL GROWTH, 2006, 292 (02) :494-499
[7]   Electronic structure of non-centrosymmetric AgCd2GaS4 and AgCd2GaSe4 single crystals [J].
Bekenev, V. L. ;
Bozhko, V. V. ;
Parasyuk, O. V. ;
Davydyuk, G. E. ;
Bulatetska, L. V. ;
Fedorchuk, A. O. ;
Kityk, I. V. ;
Khyzhun, O. Y. .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2012, 185 (12) :559-566
[8]  
Bodnar IV, 1998, RUSS J INORG CHEM+, V43, P1783
[9]   Growth and properties of the single AgCd2GaSe4 crystals [J].
Bozhko, V. V. ;
Bulatetska, L. V. ;
Davydyuk, G. Ye. ;
Parasyuk, O. V. ;
Tretyak, A. P. ;
Vainorius, N. ;
Kazukauskas, V. .
JOURNAL OF CRYSTAL GROWTH, 2011, 330 (01) :5-8
[10]   Crystal structure of the new quaternary phase AgCd2GaS4 and phase diagram of the quasi-binary system AgGaS2-CdS [J].
Chykhrij, SI ;
Parasyuk, OV ;
Halka, VO .
JOURNAL OF ALLOYS AND COMPOUNDS, 2000, 312 (1-2) :189-195