Mechanism of Selective Oxidations of Hydrocarbons with Hydrogen Peroxide Catalyzed by Metalloporphyrins

被引：0

作者：

Li Fengying ^{[1
]}

Liu Ye ^{[1
]}

Wang Xia ^{[1
]}

He Xiaoshuang ^{[1
]}

Ding Xia ^{[1
]}

机构：

[1] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

来源：

PROGRESS IN CHEMISTRY | 2008年 / 20卷 / 11期

关键词：

iron porphyrins; manganese porphyrins; selective oxidation; mechanism; hydrogen peroxide;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recent researches on mechanism of hydrocarbon selective oxidations with hydrogen peroxide catalyzed by metalloporphyrins including iron porphyrins and manganese porphyrins are reviewed in this paper. The strategies to promote heterolytic cleavage of hydrogen peroxide to facilitate the formation of active high valent metal-oxo species are discussed in detail.

引用

页码：1635 / 1641

页数：7

共 56 条

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