Study of Intermolecular Interaction of Allyl Chloride with Acetone Through Dielectric and Volumetric Properties

The static dielectric constant (epsilon(s)) and relaxation time (tau) are determined from complex permittivity spectra of Allyl Chloride (ALC) with Acetone (ACE), which are obtained using the Time Domain Reflectometry (TDR) technique in microwave frequency range 10 MHz to 10 GHz. Density (rho) and refractive index (n(D)) were also measured. These parameters are used to determine excess dielectric constant, excess molar volume, and excess molar refraction. The excess parameter is fitted to Redlich-Kister(RK) equation. The values of excess parameters are positive in ALC rich region whereas in ACE rich region are negative.