Facile fabrication of highly efficient g-C3N4/BiFeO3 nanocomposites with enhanced visible light photocatalytic activities

被引:109
作者
Wang, Xingfu [1 ,2 ]
Mao, Weiwei [1 ,2 ]
Zhang, Jian [1 ]
Han, Yumin [1 ]
Quan, Chuye [1 ]
Zhang, Qiaoxia [1 ]
Yang, Tao [1 ]
Yang, Jianping [2 ]
Li, Xing'ao [1 ]
Huang, Wei [1 ,3 ,4 ]
机构
[1] NUPT, SMSE, IAM, KLOEID,SICOEID, Nanjing 210023, Jiangsu, Peoples R China
[2] NUPT, Sch Sci, Nanjing 210023, Jiangsu, Peoples R China
[3] Nanjing Tech Univ NanjingTech, Natl Synergist Innovat Ctr Adv Mat SICAM, Key Lab Flexible Elect KLOFE, Nanjing 211816, Jiangsu, Peoples R China
[4] Nanjing Tech Univ NanjingTech, IAM, Nanjing 211816, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
g-C3N4; BiFeO3; Nanocomposites; Photocatalysis; HYDROTHERMAL SYNTHESIS; HETEROJUNCTIONS; HYBRID; NANOPARTICLES; DEGRADATION; G-C3N4;
D O I
10.1016/j.jcis.2015.01.090
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Graphitic carbon nitride/bismuth ferrite (g-C3N4/BiFeO3) nanocomposites with various g-C3N4 contents have been synthesized by a simple method. After the deposition-precipitation process, the novel BiFeO3 spindle-like nanoparticles with the size of similar to 100 nm were homogeneously decorated on the surfaces of the C3N4 nanosheets. A possible deposition growth mechanism is proposed on the basis of experimental results. The as-prepared g-C3N4/BiFeO3 composites exhibit high efficiency for the degradation of methyl orange (MO) under visible light irradiation, which can be mainly attributed to the synergic effect between g-C3N4 and BiFeO3. The ability to tune surface and interfacial characteristics for the optimization of photophysical properties suggests that the deposition growth process may enable formation of hybrids suitable for a range of photocatalytic applications based on g-C3N4. (C) 2015 Elsevier Inc. All rights reserved.
引用
收藏
页码:17 / 23
页数:7
相关论文
共 37 条
  • [1] [Anonymous], 2001, Crystallization
  • [2] PHOTOELECTROLYSIS AND PHYSICAL-PROPERTIES OF SEMICONDUCTING ELECTRODE WO3
    BUTLER, MA
    [J]. JOURNAL OF APPLIED PHYSICS, 1977, 48 (05) : 1914 - 1920
  • [3] One-step preparation of hollow ZnO core/ZnS shell structures with enhanced photocatalytic properties
    Chen, Wei
    Ruan, Hong
    Hu, Yin
    Li, Danzhen
    Chen, Zhixin
    Xian, Jiangjun
    Chen, Jing
    Fu, Xianzhi
    Shao, Yu
    Zheng, Yi
    [J]. CRYSTENGCOMM, 2012, 14 (19): : 6295 - 6305
  • [4] Two-step self-assembly of nanodisks into plate-built cylinders through oriented aggregation
    Cheng, Y
    Wang, YS
    Zheng, YH
    Qin, Y
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (23) : 11548 - 11551
  • [5] Switchable Ferroelectric Diode and Photovoltaic Effect in BiFeO3
    Choi, T.
    Lee, S.
    Choi, Y. J.
    Kiryukhin, V.
    Cheong, S. -W.
    [J]. SCIENCE, 2009, 324 (5923) : 63 - 66
  • [6] Higher-order organization by mesoscale self-assembly and transformation of hybrid nanostructures
    Cölfen, H
    Mann, S
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (21) : 2350 - 2365
  • [7] Visible Light Responsive Perovskite BiFeO3 Pills and Rods with Dominant {111}c Facets
    Fei, Linfeng
    Yuan, Jikang
    Hu, Yongming
    Wu, Changzheng
    Wang, Junling
    Wang, Yu
    [J]. CRYSTAL GROWTH & DESIGN, 2011, 11 (04) : 1049 - 1053
  • [8] Novel C3N4-CdS composite photocatalysts with organic-inorganic heterojunctions: in situ synthesis, exceptional activity, high stability and photocatalytic mechanism
    Fu, Jie
    Chang, Binbin
    Tian, Yanlong
    Xi, Fengna
    Dong, Xiaoping
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (09) : 3083 - 3090
  • [9] Visible-light photocatalytic properties of weak magnetic BiFeO3 nanoparticles
    Gao, Feng
    Chen, Xinyi
    Yin, Kuibo
    Dong, Shuai
    Ren, Zhifeng
    Yuan, Fang
    Yu, Tao
    Zou, Zhigang
    Liu, Jun-Ming
    [J]. ADVANCED MATERIALS, 2007, 19 (19) : 2889 - +
  • [10] ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS
    HOFFMANN, MR
    MARTIN, ST
    CHOI, WY
    BAHNEMANN, DW
    [J]. CHEMICAL REVIEWS, 1995, 95 (01) : 69 - 96