Enantioresolution of 2,2'-Bis(diphenylphosphino)-1,1′-binaphthyl Oxide Using Inclusion Complex with Chiral 2,2′-Dihydroxy-1,1′-binaphtyl

被引：3

作者：

Hatano, Bunpei ^{[1
]}

Hashimoto, Kazuyuki ^{[1
]}

Katagiri, Hiroshi ^{[1
]}

Kijima, Tatsuro ^{[1
]}

Murakami, Satoshi ^{[1
]}

Matsuba, Shigeru ^{[1
]}

Kusakari, Miho ^{[1
]}

机构：

[1] Yamagata Univ, Dept Biochem Engn, Grad Sch Sci & Engn, Yonezawa, Yamagata 9928510, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 77卷 / 07期

关键词：

PHOSPHINE OXIDE; ENANTIOSELECTIVE ALLYLATION; ALDOL REACTION; N-OXIDE; BINAPO; ALLYLTRICHLOROSILANES; CATALYST; LIGANDS;

D O I：

10.1021/jo202630p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An enantioresolution of 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl oxide (BINAPO) into its enantiomers was achieved using the inclusion complex with a commercially available chiral 2,2'-dihydroxy-1,1'-binaphthyl ((R)-BINOL), giving the two enantiomers with 99% ee and 72% ee, respectively.

引用

页码：3595 / 3597

页数：3

共 18 条

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