Chromium (III) catalyzed selective oxidation of sulfides to sulfoxides using 30% H2O2

被引：13

作者：

Supale, A. R. ^{[1
]}

Gokavi, G. S. ^{[1
]}

机构：

[1] Shivaji Univ, Dept Chem, Kinet & Catalysis Lab, Kolhapur 416004, Maharashtra, India

来源：

CATALYSIS LETTERS | 2008年 / 124卷 / 3-4期

关键词：

homogeneous catalysis; oxidation; sulfides; sulfoxides; chromium (III); H2O2;

D O I：

10.1007/s10562-008-9447-z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Chromium (III) is used as an efficient, recyclable catalyst for selective oxidation of sulfides. The reactions were carried out in 60% acetonitrile (v/v) using 30% H2O2. Chromium (III) forms complex with sulfides which is then oxidized by H2O2 to form sulfoxides.

引用

页码：284 / 287

页数：4

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