AN IMPROVED METHOD FOR OXIDATION OF OXIMES WITH POTASSIUM PERMANGANATE ADSORBED ON GRAPHITE REAGENT UNDER VISCOUS CONDITIONS

被引：0

作者：

Zhu, Li-Yun ^{[1
]}

Huang, Chen ^{[2
]}

Shi, Chenxiao ^{[3
]}

Lin, Fang ^{[1
]}

Zhang, Changhe ^{[4
]}

Lou, Ji-Dong ^{[1
,5
]}

机构：

[1] China Jiliang Univ, Coll Life Sci, Hangzhou 310018, Zhejiang, Peoples R China

[2] China Pharmaceut Univ, Nanjing 210009, Jiangsu, Peoples R China

[3] Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China

[4] Univ Tras Os Montes & Alto Douro UTAD, Ctr Res & Technol Agroenvironm & Biol Sci CITAB, Dept Biol & Environm, P-5001801 Vila Real, Portugal

[5] Sirnaomics Inc, Gaithersburg, MD 20879 USA

来源：

OXIDATION COMMUNICATIONS | 2012年 / 35卷 / 02期

关键词：

aldehydes; ketones; oxidation; oximes; potassium permanganate; graphite; viscous conditions; SELECTIVE OXIDATION; BENZOINS; CLEAVAGE; DICHROMATE; BENZILS; MILD;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An improved procedure for oxidative cleavage of oximes to the corresponding aldehydes and ketones with potassium permanganate adsorbed on graphite reagent under viscous conditions at room temperature in yields between 80 and 97% is described. The main advantage of the present procedure is that under viscous conditions the oxidation of the solid substrates can be carried out as a mild process with high efficiency.

引用

页码：389 / 393

页数：5

共 17 条

[1] Selective deoximation using alumina supported potassium permanganate [J].

Chrisman, W ;

Blankinship, MJ ;

Taylor, B ;

Harris, CE .

TETRAHEDRON LETTERS, 2001, 42 (29) :4775-4777

[2] Wet silica-supported permanganate:: A mild and inexpensive reagent for highly enantiomeric purity conversion of α-sulfinyl oximes and α-sulfinyl hydrazones to α-keto sulfoxides [J].

Hajipour, A. R. ;

Ruoho, A. E. .

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2004, 1 (02) :159-162

[3]

HUANG L., 2011, SYNTHETIC COMMUN, V41, P1059

[4] Solid state cleavage of oximes with potassium permanganate supported on alumina [J].

Imanzadeh, GH ;

Hajipour, AR ;

Mallakpour, SE .

SYNTHETIC COMMUNICATIONS, 2003, 33 (05) :735-740

[5] Oxidation of oximes to ketones with zeolite supported permanganate [J].

Jadhav, VK ;

Wadgaonkar, PP ;

Joshi, PL ;

Salunkhe, MM .

SYNTHETIC COMMUNICATIONS, 1999, 29 (11) :1989-1995

[6]

LOU J. D., 2012, SYNTH REACT IN PRESS

[7] Oxidation of alcohols catalyzed by a new potassium permanganate adsorbed on graphite reagent [J].

Lou, JD ;

Wang, GQ ;

Li, L ;

Zhu, LY .

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2005, 35 (04) :281-283

[8] A first example of a reaction under viscous conditions: oxidation of solid benzoins with manganese dioxide [J].

Lou, Ji-Dong ;

Lu, Xiu L. ;

Marrogi, Aizen J. ;

Li, Feng ;

Gao, Chun-Ling ;

Yu, Xiaoping .

MONATSHEFTE FUR CHEMIE, 2008, 139 (06) :609-611

[9]

Lou JD, 2011, OXID COMMUN, V34, P616

[10]

Lou JD, 2011, OXID COMMUN, V34, P53

← 1 2 →