Visible-light-harvesting organogel composed of cholesterol-based perylene derivatives

被引:441
作者
Sugiyasu, K [1 ]
Fujita, N [1 ]
Shinkai, S [1 ]
机构
[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Higashi Ku, Fukuoka 8128581, Japan
关键词
absorption; chromophores; nanostructures; self-assembly; sol-gel processes;
D O I
10.1002/anie.200352458
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A rich harvest: A visible-light-harvesting system has been created utilizing an organogel medium (see picture; the inset shows different gel mixtures). Mixing four different perylene derivatives in the gel phase sets up an energy gradient in the gel fibrils. The well-defined nanofibers harvest a wide range of light energy in the visible region (i.e., sunlight) to the energy sink in a stepwise manner.
引用
收藏
页码:1229 / 1233
页数:5
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