Novel oxo-peroxo molybdenum(VI) complexes incorporating 8-quinolinol:: synthesis, structure and catalytic uses in the environmentally benign and cost-effective oxidation method of methyl benzenes:: Ar(CH3)n (n=1, 2)

被引：59

作者：

Bandyopadhyay, R

Biswas, S

Guha, S

Mukherjee, AK

Bhattacharyya, R ^{[1
]}

机构：

[1] Jadavpur Univ, Dept Chem, Calcutta 700032, W Bengal, India

[2] Jadavpur Univ, Dept Phys, Calcutta 700032, W Bengal, India

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a904440j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A hitherto unknown distorted pentagonal bipyramidal complex, [MoO(O-2)(QO)(2)], very efficiently catalyses homogeneous liquid phase oxidation of methylbenzenes, viz. toluene and o- and p-xylenes to benzoic acid, phthalic acid and p-toluic acid respectively, using H2O2 and O-2 as oxidants.

引用

页码：1627 / 1628

页数：2

共 14 条

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