Three metal-organic coordination polymers constructed by 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene

被引：4
|
作者：
Liu, Lei [2 ]
Han, Bing [2 ]
Liang, Xiaoqiang [1 ]
Yang, Zhi [2 ]
Jia, Jiangtao [1 ]
Sun, Fuxing [1 ]
Zhu, Guangshan [1 ]
机构：
[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
[2] Jilin Univ, Coll Chem, Teaching & Res Ctr Chem, Changchun 130021, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2013年 / 1047卷
基金：
中国国家自然科学基金;
关键词：
Metal-organic coordination polymer 1,2,4-Triazole; 1,4-Bis(1,2,4-triazol-1-ylmethyl)benzene; FRAMEWORKS; COMPLEXES; TOPOLOGY; LIGAND; CO(II); 1D;
D O I：
10.1016/j.molstruc.2013.04.067
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Three new diverse structural metal-organic coordination polymers, [Pb(anti-btx)(H2O) (NO3)(2)] (1), [Cd(anti-btx)(H2O)(2)(NO3)(2)] (2), and [Zn(anti-btx) (syn-btx)(H2O)(2)] (NO3)(2) (3) [btx = 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene], have been prepared under room temperature. Their structures were characterized by elemental analysis, IR, single-crystal X-ray diffraction analysis and thermogravimetric (TG) analysis. 1 is a 1D serration chain; 2 is an infinite ladder 10 chain; and 3 is generated as an infinite 10 chain. The 1D chain of the three complexes are all formed 3D framework through hydrogen bondings and pi-pi stacking interactions. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：338 / 343
页数：6
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