Three metal-organic coordination polymers constructed by 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene

被引：4

作者：

Liu, Lei ^{[2
]}

Han, Bing ^{[2
]}

Liang, Xiaoqiang ^{[1
]}

Yang, Zhi ^{[2
]}

Jia, Jiangtao ^{[1
]}

Sun, Fuxing ^{[1
]}

Zhu, Guangshan ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

[2] Jilin Univ, Coll Chem, Teaching & Res Ctr Chem, Changchun 130021, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2013年 / 1047卷

基金：

中国国家自然科学基金;

关键词：

Metal-organic coordination polymer 1,2,4-Triazole; 1,4-Bis(1,2,4-triazol-1-ylmethyl)benzene; FRAMEWORKS; COMPLEXES; TOPOLOGY; LIGAND; CO(II); 1D;

D O I：

10.1016/j.molstruc.2013.04.067

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Three new diverse structural metal-organic coordination polymers, [Pb(anti-btx)(H2O) (NO3)(2)] (1), [Cd(anti-btx)(H2O)(2)(NO3)(2)] (2), and [Zn(anti-btx) (syn-btx)(H2O)(2)] (NO3)(2) (3) [btx = 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene], have been prepared under room temperature. Their structures were characterized by elemental analysis, IR, single-crystal X-ray diffraction analysis and thermogravimetric (TG) analysis. 1 is a 1D serration chain; 2 is an infinite ladder 10 chain; and 3 is generated as an infinite 10 chain. The 1D chain of the three complexes are all formed 3D framework through hydrogen bondings and pi-pi stacking interactions. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：338 / 343

页数：6

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