Hydrogen diazide -: Synthesis and crystal structure of PPh4[N3HN3]

被引：0
|
作者：
Neumüller, B [1 ]
Schmock, F [1 ]
Dehnicke, K [1 ]
机构：
[1] Univ Marburg, Fac Chem, D-35032 Marburg, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 08期
关键词：
hydrogen diazide; crystal structure;
D O I：
10.1002/(SICI)1521-3749(199908)625:8<1243::AID-ZAAC1243>3.0.CO;2-N
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
PPh4[N3HN3] has been prepared from PPh4N3 and Me3SiN3 by the reaction with water or ethanol forming colourless nonexplosive crystal needles, which were characterized by IR spectroscopy and by a crystal structure determination. Space group C2/c, Z = 12, lattice dimensions at -70 degrees C: a = 3782.4(3), b = 727.8(2), c = 2512.4(2) pm, beta = 110.13(1)degrees, R = 0.0841. The [N3HN3](-) ion is characterized by an asymmetric N-H ... N hydrogen bridge with a NN distance of 272(1) pm.
引用
收藏
页码：1243 / 1245
页数：3
相关论文
共 50 条
  • [1] Synthesis and crystal structure of PPh4[PhICl3]
    Grebe, J
    Geiseler, G
    Harms, K
    Dehnicke, K
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1999, 54 (01): : 140 - 143
  • [2] Synthesis and crystal structure of PPh4[PhICl3]
    Grebe, Jutta
    Geiseler, Gertraud
    Harms, Klaus
    Dehnicke, Kurt
    Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1999, 54 (01): : 140 - 143
  • [3] THE CRYSTAL-STRUCTURES OF PPH4[SNCL3] AND PPH4[SNBR3]
    MULLER, U
    MRONGA, N
    SCHUMACHER, C
    DEHNICKE, K
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1982, 37 (09): : 1122 - 1126
  • [4] Synthesis and crystal structure of (PPh4)3[Re2NCl10]
    Schwarz, S
    Strähle, J
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2004, 630 (15): : 2717 - 2719
  • [5] The syntheses and crystal structures of [PPh4][In(SePh)4] and [PPh4][In(SePh)3(SeH)]
    Smith, DM
    Ibers, JA
    POLYHEDRON, 1998, 17 (11-12) : 2105 - 2108
  • [6] (PPH4)2[MON(N3)3CL]2 - SYNTHESIS, IR-SPECTRUM, AND CRYSTAL-STRUCTURE
    JANSEN, K
    SCHMITTE, J
    DEHNICKE, K
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1987, 552 (09): : 201 - 209
  • [7] PPH4[AS3S3CL4] AND PPH4[AS3S3BR4]
    MOHAMMED, AT
    KRUG, V
    MULLER, U
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1988, 557 (02): : 91 - 97
  • [8] SYNTHESIS AND CRYSTAL-STRUCTURE OF (PPH4)2TE4
    WOLKERS, H
    SCHREINER, B
    STAFFEL, R
    MULLER, U
    DEHNICKE, K
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1991, 46 (08): : 1015 - 1019
  • [9] Preparation and crystal structure of tetraphenylphosphonium triiodotetrabromide [PPh4][I3Br4]
    Minkwitz, R
    Berkei, M
    Ludwig, R
    INORGANIC CHEMISTRY, 2001, 40 (01) : 25 - 28
  • [10] Synthesis and crystal structure of the hydrogen polyphosphide bis(tetraphenylphosphonium) hydrogenheptaphosphide-ammonia(1/3) (PPh4)2HP7 • 3NH3
    Aschenbrenner, AC
    Korber, N
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2004, 630 (01): : 31 - 32
12345